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'Phosphorus Phosphorus Bonds' in keywords Facet   section ZfN Section B  [X]
Facet   Publication Year 1982  [X]
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1982[X]
1Author    HerbertW. Roesky, Habibollah Djarrah, Mathias Noltemeyer, GeorgeM. SheldrickRequires cookie*
 Title    Über Reaktionen von Pyrrolidinium-bis(diethylphosphoryl)phosphinidin mit Chromcarbonylkomplexen Reaction of Pyrrohdinium-bis(diethylphosphoryl)phosphinidine with Chromiumcarbonyl Complexes  
 Abstract    The reaction of [H2NC4H8]P[P(0)(0C2H5)2]2 with Cr(CO)5THF and Cr(CO)4C7H8 results in the formation of the 1: 1 and 1:2 chromium pentacarbonyl complexes. The 1: 1 complex was characterized on the basis of an X-ray analysis. It crvstallizes in the space group P I with a = 1091.9(10), 6=1164.1(12), c ='l356.4(9) pm, a = 108.89(6), ß= 97.57(7), y = 116.24(6), and Z — 2. The average P-P bond length was found to be 215.8 pm. 
  Reference    Z. Naturforsch. 37b, 1580—1583 (1982); eingegangen am 9. August 1982 
  Published    1982 
  Keywords    Crystal Structure, 31 P NMR Spectra, Phosphorus-Phosphorus Bonds, Chromium 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1580.pdf 
 Identifier    ZNB-1982-37b-1580 
 Volume    37