| | 1 | Author
| OttoJ. Scherer, Heribert Jungmann | Requires cookie* | | | Title
| Phosphor-Ylid-Komplexe des Platins Phosphorus Ylide Complexes of Platinum  | | | | Abstract
| The interaction of eis/trans-[Pt(PPI13) 2 (CH2CI)Cl] (1) with Ph 3 P gives the ylide complex cis-[Pt(PPh 3) 2 (CH 2 PPh 3)Cl]Cl (2), which forms cis-[Pt(PPh 3)(CH 2 PPh 3)Cl 2 ] (3) on heating in benzene. In CH 2 C1 2 , Ph 3 P is added again quanti-tatively with formation of 2. Irradiation of 3 with a 500 W lamp yields cw-Cl 2 Pt(PPh 3) 2 . The ylide complexes 4 and 6 were prepared by treatment of 3 with (Me2N) 3 P or Ph 3 As. 3 and Ph 2 P(CH 2) 2 PPh 2 form the chelate ylide com-plex 6. | | | |
Reference
| Z. Naturforsch. 36b, 1663—1665 (1981); eingegangen am 26. August 1981 | | | |
Published
| 1981 | | | |
Keywords
| Phosphorus Ylide Complexes, Synthesis, NMR Spectra | | | |
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| 36 | |
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