1 | Author | Siegfried Pohl | Requires cookie* |
Title | Cis-2-telluro-1.3.22 5 .4A 3 -diazadiphosphetidin - Kristallstruktur eines in Lösung fluktuierenden Redoxsystems Cis-2-telhirium-1.3.2/ 5 .4A 3 -diazadiphosphetidine - Crystal Structure of a Redox System Fluctuating in Solution ![]() | ||
Abstract | The crystal structure of the title compound was determined from single crystal X-ray data. The compound crystallises in the orthorhombic space group Pnma. In contrast to the solution where fluctuating P-Te bonds have been established by NMR analyses the crystals contain isolated molecules with fixed P-Te bonds (bond length: 235.4 pm). The four-membered phosphorus nitrogen ring exhibits significant deviations from planarity. The P-N bond lengths were found to be 168.3 and 175.0 pm, respectively. | ||
Reference | Z. Naturforsch. 33b, 610—613 (1978); eingegangen am 17. Februar 1978 | ||
Published | 1978 | ||
Keywords | Crystal Structure, Four-Membered Phosphorus Nitrogen Ring, Phosphorus Tellurium Compound | ||
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