| | 1 | Author
| Antonios Antoniadis, Wolfgang Hiller, Udo Kunze, Schaal Herberth, Joachim Strähle | Requires cookie* | | | Title
| Phosphinsubstituierte Chelatliganden, VI [1] Kristallstrukturen von Tetracarbonyl(diphenylphosphino -N-phenylthioformimidato -P,S )mangan(I) und Tetracarbonyl(diphenylthiophosphoryl-N-phenylthioformimidato-S,S')mangan(I) Phosphine Substituted Chelate Ligands, VI [1] Crystal Structures of Tetracarbonyl(diphenylphosphino-N-phenylthioformimidato-P,S)- manganese(I) and Tetracarbonyl(diphenylthiophosphoryl-X-phenylthioformimidato-S.S')- manganese(I)  | | | | Abstract
| The phosphinothioformimidato complex (CO)4MnSC(NPh)PPli2 (1) crystallizes tri-clinic in the space group PI with lattice constants a = 989.4(9) pm, b — 1042.0(8) pm, c = 1088.5(8) pm, a = 91.45(4)°, ß = 97.10(4)°, y = 100.53(5)°. The four-membered chelate I 1 ring Mn-P-C-S is folded over the P-S edge by a dihedral angle of 167.1°. The crystal I 1 system of the thiophosphoryl thioformimidato complex (CO)4MnSC(NPh)P(S)Ph2 (2) is monoclinic with the space group P2i/c, and the lattice parameters are a = 1109.5(3) pm, b = 966.0(3) pm, c = 2256.7(3) pm, 0=103.11(2)°. The chelate ligand is linked to the metal by two S atoms forming a five-membered ring in the "envelope" conformation with the thiophosphoryl S atom at the apical position. | | | |
Reference
| Z. Naturforsch. 37b, 1289—1293 (1982); eingegangen am 7. Mai 1982 | | | |
Published
| 1982 | | | |
Keywords
| Crystal Structure, Chelate Ligands, Phosphinothioformimidate, Thiophosphorylthioformimidate, Manganese Complexes I 1 | | | |
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| default:Reihe_B/37/ZNB-1982-37b-1289.pdf | | | | Identifier
| ZNB-1982-37b-1289 | | | | Volume
| 37 | |
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