| | 1 | Author
| Udo Kunze, Antonios Antoniadis | Requires cookie* | | | Title
| Phosphinsubstituierte Chelatliganden, IV [1] Neue Diphenylphosphinoformamid-Komplexe des Mangans und Eisens Phosphine Substituted Chelate Ligands, IV [1] New Diphenylphosphino Formamide Complexes of Manganese and Iron  | | | | Abstract
| The phosphino and (thio)phosphoryl formamides la, b, 2a-c, 3a, b, 4a, b which were partially unknown are synthesized by various methods, and their reactions with carbonyl-metal halides of manganese and iron are described. The formation of the P,N-and S,N-coordinate chelate complexes, (CO)4MnL (5 a, 8a), is limited to the N-phenyl derivatives la and 4a. With L = 2a, b, the unidentate P-coordination predominates. Thus, the carbonylmetal halide complexes cis-(CO)4Mn(X)L (6a, b: X = CI, 7a, b: X = Br) and 7? 5 -C5H5(CO)Fe(X)L (9a, b: X = I, 10a, b: X = Br) are obtained. Due to the low stability of the formamide complexes, their formation is always accompanied by isocyanate elimi-nation as a side-reaction. | | | |
Reference
| Z. Naturforsch. 37b, 560—567 (1982); eingegangen am 17. November 1981 | | | |
Published
| 1982 | | | |
Keywords
| Chelate Ligands, Phosphino Formamide, Manganese Complexes, Iron Complexes, Isocyanate Elimination | | | |
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| default:Reihe_B/37/ZNB-1982-37b-0560.pdf | | | | Identifier
| ZNB-1982-37b-0560 | | | | Volume
| 37 | |
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