| | 1 | Author
| Joachim Bruckmann, Carl Krüger, Frank Lutz | Requires cookie* | | | Title
| Systematic Structural Investigations on Phosphines  | | | | Abstract
| This work contributes to the systematic investigation of phosphines. In an attem pt to deter mine the nature, shape, volume and direction of the lone pairs at the phosphorus atoms in phosphines, high resolution X-ray structure analyses of triphenylphosphine, tris(p-methoxy-phenyl)phosphine, bis(2,4,6-triisopropylphenyl)phosphine, 1,1 -bis(diphenylphosphino)ethene and 4,5,6-triphenyl-4-phosphaspiro[2.4]hept-5-en have been carried out. New valence force field param eters (TRIPOS force field) are presented which were developed on the basis of the molecular structures of the free phosphines. The results of crystal growing experiments using zone melting techniques are summarized. | | | |
Reference
| Z. Naturforsch. 50b, 351—360 (1995); received Septem ber 20 1994 | | | |
Published
| 1995 | | | |
Keywords
| Phosphines, Molecular Modeling, Crystal Growing, High Resolution X-Ray Analysis | | | |
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| default:Reihe_B/50/ZNB-1995-50b-0351.pdf | | | | Identifier
| ZNB-1995-50b-0351 | | | | Volume
| 50 | |
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