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'Phosphines' in keywords Facet   Publication Year 1995  [X]
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1Author    Joachim Bruckmann, Carl Krüger, Frank LutzRequires cookie*
 Title    Systematic Structural Investigations on Phosphines  
 Abstract    This work contributes to the systematic investigation of phosphines. In an attem pt to deter­ mine the nature, shape, volume and direction of the lone pairs at the phosphorus atoms in phosphines, high resolution X-ray structure analyses of triphenylphosphine, tris(p-methoxy-phenyl)phosphine, bis(2,4,6-triisopropylphenyl)phosphine, 1,1 -bis(diphenylphosphino)ethene and 4,5,6-triphenyl-4-phosphaspiro[2.4]hept-5-en have been carried out. New valence force field param eters (TRIPOS force field) are presented which were developed on the basis of the molecular structures of the free phosphines. The results of crystal growing experiments using zone melting techniques are summarized. 
  Reference    Z. Naturforsch. 50b, 351—360 (1995); received Septem ber 20 1994 
  Published    1995 
  Keywords    Phosphines, Molecular Modeling, Crystal Growing, High Resolution X-Ray Analysis 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0351.pdf 
 Identifier    ZNB-1995-50b-0351 
 Volume    50