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1	Author		Requires cookie*
	Title	Zur Stereochemie der Phosphinoxydspaltung von R -Methyl -phenyl-a -naphthyl -allyl-phosphoniumbromid The Stereochemistry of the Phosphine Oxide Cleavage of R-( + )-Methyl-phenyl-a-naphthyl-allyl-phosphonium Bromide
	Abstract	The stereochemical course of the 'phosphine oxide cleavage' of chiral R-(+)-methyl-phenyl-a-naphthyl-allyl-phosphonium bromide is reported. While the a-naphthyl group is cleaved by alkali with predominant retention of configuration at the central phosphorus atom, the allyl group is split off with predominant inversion.
	Reference	(Z. Naturforsch. 30b, 119—123 [1975]; eingegangen am 11. September 1974)
	Published	1975
	Keywords	Phosphine Oxide Cleavage, Stereochemistry, Chiral Phosphonium Salts
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	TEI-XML for	default:Reihe_B/30/ZNB-1975-30b-0119.pdf
	Identifier	ZNB-1975-30b-0119
	Volume	30

2	Author	Reiner Luckenbach	Requires cookie*
	Title	Zur Stereochemie der Phosphinoxidspaltung chiraler acyclischer Phosphoniumsalze The Stereochemistry of the Phosphine Oxide Cleavage of Chiral Acyclic Phosphonium Salts
	Abstract	The stereochemistry of the 'phosphine oxide cleavage' of 37 different chiral acyclic quaternary phosphonium salts under various reaction conditions is presented and discussed. Über den sterischen Verlauf der unter der Be-zeichnung "Phosphinoxidspaltung" bekannten Um-setzung quartärer acychscher chiraler Phosphonium-salze mit Alkalihydroxiden zu tertiären Phosphin-oxiden und Kohlenwasserstoffen gemäß der Glei-chung (1)
	Reference	(Z. Naturforsch. 31b, 1127—1134 [1976]; eingegangen am 20. April 1976)
	Published	1976
	Keywords	Chiral Phosphonium Salts, Chiral Phosphine Oxides, Stereochemistry, Phosphine Oxide Cleavage, Phosphorane Intermediates
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	TEI-XML for	default:Reihe_B/31/ZNB-1976-31b-1127.pdf
	Identifier	ZNB-1976-31b-1127
	Volume	31