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Title | Zur Stereochemie der Phosphinoxydspaltung von R -Methyl -phenyl-a -naphthyl -allyl-phosphoniumbromid The Stereochemistry of the Phosphine Oxide Cleavage of R-( + )-Methyl-phenyl-a-naphthyl-allyl-phosphonium Bromide ![]() | ||
Abstract | The stereochemical course of the 'phosphine oxide cleavage' of chiral R-(+)-methyl-phenyl-a-naphthyl-allyl-phosphonium bromide is reported. While the a-naphthyl group is cleaved by alkali with predominant retention of configuration at the central phosphorus atom, the allyl group is split off with predominant inversion. | ||
Reference | (Z. Naturforsch. 30b, 119—123 [1975]; eingegangen am 11. September 1974) | ||
Published | 1975 | ||
Keywords | Phosphine Oxide Cleavage, Stereochemistry, Chiral Phosphonium Salts | ||
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