| | 1 | Author
| Von Elementen, V. Hauptgruppe, Mathias Höfler, Heinz Hausmann, Wilhelm Saal | Requires cookie* | | | Title
| Austauschreaktionen an komplexgebundenen Liganden Darstellung und Reaktionen von Komplexen des Typs 7r-C5H5Mn(CO)2L (L = Phosphid, Amid) Preparation and Reactions of Complexes of the Type 7r-C5H5Mn(CO)2L (L = phosphide, amide)  | | | | Abstract
| The reduction of the complexes C5H5Mn(CO)2L (L = P(C6H5)2C1, P(C6H5)(Et)Cl and P(C6H5)C12) with Na in liquid NH3 yields the complexes C5H5Mn(CO)2L' (L' = P(C6H5)2Na, P(C6H5)(Et)Na and P(C6H5)Na2). The reaction of these complexes with CH3J and of CpMn(CO)2P02Na with H20, CH2C12, CCI4, J2 and CH3COCI are described. Furthermore it has been found, that «-butyl-lithium yields C5H5Mn(CO)2NMe2Li if reacted with C5H5Mn(CO)2NMe2H. | | | |
Reference
| (Z. Naturforsch. 31b, 790—794 [1976]; eingegangen am 4. September/11. Dezember 1975) | | | |
Published
| 1976 | | | |
Keywords
| Amino Complexes, Metallation, Phosphine Complexes | | | |
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| default:Reihe_B/31/ZNB-1976-31b-0790.pdf | | | | Identifier
| ZNB-1976-31b-0790 | | | | Volume
| 31 | |
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