| | 1 | Author
| E. Kkehard Lindner, Petra Neese | Requires cookie* | | | Title
| Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, LII [1] Bindungs-und Strukturverhältnisse von Phosphidocobaltaten in Lösung und im festen Zustand Preparation and Properties of, and Reactions with, M etal-Containing Heterocycles, LII [1] Bonding and Structural Conditions of Phosphidocobaltates in Solution and in Solid State  | | | | Abstract
| Reduction o f [(O C)3C oPPh2]" (la) with excess sodium granules affords [(O C)3CoPPh2]N a2 (3a) in solution as well as in solid state. H ow ever, in analogous reactions o f [(O C)3C oP R 2H ]2 (lb : R = C6H n ; lc : R = r-Bu) with excess sodium granules the m onovalent anionic com plexes [(O C)3C oP R 2H ]Na (2b, c) are obtained in TH F solution. 2 b , c cannot be isolated in solid state. A fter removal of TH F from their solutions the purified residues were identified by elem ental | | | |
Reference
| Z. Naturforsch. 41b, 870 (1986); eingegangen am 26. Februar 1986 | | | |
Published
| 1986 | | | |
Keywords
| Phosphidocobaltates, Structure, Reactivity, IR Spectra, N M R Spectra | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/41/ZNB-1986-41b-0870.pdf | | | | Identifier
| ZNB-1986-41b-0870 | | | | Volume
| 41 | |
|
