| | 1 | Author
| Hans-Christian Böttcher, Kurt Merzweiler, Clemens Bruhn | Requires cookie* | | | Title
| Synthesis and X -R a y C rysta l Structure o f the Heterobim etallic Com plex [F eR h (/x-C O )(C O )3(/i-P B u '2)(M -Ph2PC H 2PPh2)]  | | | | Abstract
| The reaction of the phosphido-bridged metal carbonyl [FeRh(CO)ö(At-PBu2)] (1) with dppm [dppm = bis(diphenylphosphino)methane] leads to the heterobimetallic complex [FeRh(/z-CO)(CO)3()U-PBu2)(/i-dppm)] (2) in good yields. The molecular structure of 2 was determined at room temperature [triclinic, space group Pi, a = 9.509(6), b = 13.637(5), c = 14.926(8) A, q = 81.38(4), ß = 82.75(4), 7 = 71.25(4)°]. The compound acts as a homogeneous catalyst precursor in the hydroformylation reaction of ethylene, but it decomposes during this process. | | | |
Reference
| Z. Naturforsch. 52b, 810—814 (1997); received April 15 1997 | | | |
Published
| 1997 | | | |
Keywords
| Dinuclear Iron Rhodium Complex, Phosphido-Bridged, Crystal Structure, Homogeneous Catalysis, Hydroformylation | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0810.pdf | | | | Identifier
| ZNB-1997-52b-0810 | | | | Volume
| 52 | |
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