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'Phosphido Bridged' in keywords Facet   Publication Year 1997  [X]
Facet   section ZfN Section B  [X]
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1Author    Hans-Christian Böttcher, Kurt Merzweiler, Clemens BruhnRequires cookie*
 Title    Synthesis and X -R a y C rysta l Structure o f the Heterobim etallic Com plex [F eR h (/x-C O )(C O )3(/i-P B u '2)(M -Ph2PC H 2PPh2)]  
 Abstract    The reaction of the phosphido-bridged metal carbonyl [FeRh(CO)ö(At-PBu2)] (1) with dppm [dppm = bis(diphenylphosphino)methane] leads to the heterobimetallic complex [FeRh(/z-CO)(CO)3()U-PBu2)(/i-dppm)] (2) in good yields. The molecular structure of 2 was determined at room temperature [triclinic, space group Pi, a = 9.509(6), b = 13.637(5), c = 14.926(8) A, q = 81.38(4), ß = 82.75(4), 7 = 71.25(4)°]. The compound acts as a homogeneous catalyst precursor in the hydroformylation reaction of ethylene, but it decomposes during this process. 
  Reference    Z. Naturforsch. 52b, 810—814 (1997); received April 15 1997 
  Published    1997 
  Keywords    Dinuclear Iron Rhodium Complex, Phosphido-Bridged, Crystal Structure, Homogeneous Catalysis, Hydroformylation 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0810.pdf 
 Identifier    ZNB-1997-52b-0810 
 Volume    52