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'Phosphazene' in keywords Facet   section ZfN Section B  [X]
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1997 (1)
1996 (2)
1Author    Jochen Ellermann, Peter Gabold, FalkA. Knoch, MatthiasM. Oll, Astrid Schmidt, Martin SchützRequires cookie*
 Title    Chemie polyfunktioneller Moleküle, 120 [1] Synthesen und Kristallstrukturanalysen von Tris(imido-tetraphenyl- diphosphinato-0,0')eisen(III) und des PP-verknüpften Phosphazens Ph2P-N=PPh2-PPh2=N-PPh2 Chemistry o f Polyfunctional M olecules, 120 [11 Syntheses and Crystal Structures o f Tris(imido-tetraphenyl-diphosphinato-0,0')iron(III) and o f the PP-Connected Phosphazene Ph2P-N=PPh2-PPh2=N-PPh2  
 Abstract    While the reaction of anhydrous iron(III) chloride with the chelate ligand [(C6H5)2P(0)]2NH (6) is an efficient way to synthesize the new tricyclic compound imido-tetraphenyl-diphosphinato-0,0'iron(III), [Fe{0-P(Ph2)=N-P(Ph2)= 0 }3] (4), treatment of [(C6H5)2P]2NLi (1) with anhydrous iron(III) fluoride in THF represents a simple route to obtain the phosphorus-phosphorus connected species Ph2P-N=PPh2-PPh2=N-PPh2(7). Both compounds were charac­ terized by X-ray crystallography, 'H ,31 P {1H}, 13C {1H} NMR, IR, Raman and mass spectra. 
  Reference    Z. Naturforsch. 51b, 201—208 (1996); eingegangen am 24. Juli 1995 
  Published    1996 
  Keywords    Phosphazene, Iron Complexes, Synthesis, X-Ray 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0201.pdf 
 Identifier    ZNB-1996-51b-0201 
 Volume    51 
2Author    Crystal, FrankH. Artm Anna, D. Ietrich, M. Ootz, Reinhard SchwesingerRequires cookie*
 Title    Zur Kristallchemie ungeladener Phosphazen-Basen, I [1] Strukturen zweier Hydrate und eines Acetats von Tris(dimethylamino)methyliminophosphoran  
 Abstract    C hem istry o f U ncharged Phosphazene Bases, I [ 1 ] Structures o f Two H ydrates and an A cetate o f T ris(dim ethylam ino)m ethylim inophosphorane Two hydrates and an acetate of the uncharged, very strong phosphazene base tris(dimethylamino)methyliminophosphorane, (Me2N)3P=NMe (for short Me-P]), have been characterized by their crystal structures. A monohydrate, Me-P, • H:0 , mp. 3°C, is monoclinic 
  Reference    Z. Naturforsch. 51b, 1369—1374 (1996); eingegangen am 11. März 1996 
  Published    1996 
  Keywords    Crystal Structure, Hydrate, Hydrogen Bonding, Phosphazene, Uncharged Base 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-1369.pdf 
 Identifier    ZNB-1996-51b-1369 
 Volume    51 
3Author    Jochen Ellermann3, Martin Schütz3, FrankW. Heinemann3, Matthias Moll3, Walter BauerbRequires cookie*
 Title    Chemie polyfunktioneller Moleküle, 127 [1] PPh2-Eliminierung aus dem PP-verknüpften Phosphazen Ph2P-N=PPh2-PPh2=N-PPh2 mit [C5H5Fe(CO)(/x-CO)]2; Kristallstrukturanalyse des Phosphazen-Derivats Chemistry of Polyfunctional Molecules, 127 [1] PPh2 Elimination from the PP Connected Phosphazene Ph2P-N=PPh2-PPh2=N-PPh-, with [C5H5Fe(CO)(^-CO)]2; Crystal Structure of the Phosphazene Derivative  
 Abstract    The reaction of Ph2P-N=PPh2-PPh2=N-PPh2 (Ph = C6H5, 2) with [CpFe(CO)(^-CO)]2 (Cp = C5H5, 3) yields under elimination of a PPh2-group from 2 and cleavage of the Fe-Fe bond in 3 the monocyclic ferraphosphazene complex Cp(OC)Fe-Ph2P-N=PPh2=N-PPh2 (4) and Ph2P-PPh2 (5). In a side reaction the P-P bond of 2 is also cleaved in a redox process to give Cp(OC)Fe-Ph2P-N-PPh2 (7). Compound 4 has been characterized by a crystal structure determination. 
  Reference    Z. Naturforsch. 52b, 795—800 (1997); eingegangen am 7. April 1997 
  Published    1997 
  Keywords    Phosphazene, Iron Complexes, X-Ray, Elimination of PPh2, Cleavage of PP 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0795.pdf 
 Identifier    ZNB-1997-52b-0795 
 Volume    52