| | 1 | Author
| Giorgio Concas, Giorgio Spano, Marzia Carrada, Marco Bettinelli, Adolfo Speghini | Requires cookie* | | | Title
| Local Structure of Europium Sites in Oxide Glasses by Nuclear Gamma Resonance  | | | | Abstract
| The symmetry and disorder of the Eu 3+ site was investigated in some phosphate and borate glasses by means of 151 Eu Mössbauer spectroscopy. The quadrupole interaction parameter, which is due to the distortion of the Eu site compared to a cubic symmetry, has been measured together with the asymmetry parameter, which points out the absence of a threefold or fourfold axis of symmetry at the rare earth site. The correlation of the isomer shift with the optical basicity of the glass indicates a covalent component with 6s character in the Eu-0 bond. The axial component of the electric field gradient at the Eu site is also correlated with the optical basicity. | | | |
Reference
| Z. Naturforsch. 54a, 539—544 (1999); received August 5 1999 | | | |
Published
| 1999 | | | |
Keywords
| Europium, Oxide Glasses, Phosphates, Borates, 15 'Eu Mössbauer Spectroscopy | | | |
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| default:Reihe_A/54/ZNA-1999-54a-0539.pdf | | | | Identifier
| ZNA-1999-54a-0539 | | | | Volume
| 54 | |
| 2 | Author
| A. Chrissanthopoulos3, C. Pouchan3, G. N. Papatheodorou5 | Requires cookie* | | | Title
| Structural Investigation of Vanadium -Sodium Metaphosphate Glasses | | | | Abstract
| Paper presented a t the NATO A dvanced Study Institute, M ay 4-1 4 , 2001 (Kas, Turkey) The structure of the glass forming system (V20 5)x -(Na20 • P205)(1_^), (jc = 0-0.4), has been inves tigated using Raman spectroscopy. The stretching vibrations of various phosphate groups, connected to phosphorus or vanadium atoms, have been assigned. Variation o f the composition leads to structural changes where the sodium metaphosphate -P-O-P-chains break and then reconnect with the oxovana-dium units forming a -V-O-P-network structure. | | | |
Reference
| Z. Naturforsch. 56a, 773—7 (2001); received August 8 2001 | | | |
Published
| 2001 | | | |
Keywords
| Vanadium, Phosphates, Vanadium Glass, Raman Spectroscopy, Metaphosphates | | | |
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| default:Reihe_A/56/ZNA-2001-56a-0773.pdf | | | | Identifier
| ZNA-2001-56a-0773 | | | | Volume
| 56 | |
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