| 1 | Author
| D. Frerichs, Hk Müller-Buschbaum | Requires cookie* | | Title
| Vier verschiedene Koordinationspolyeder um Cu2+ im Oxid-Arsenat-Phosphat Cu0  | | | Abstract
| (Cu,M g)3(As1_xPJt:0 4)2 (x = 0,3) Four Different Coordination Polyhedra Around Copper in the Oxide-Arsenate-Phosphate C u0(C u,M g)3(A s,_xP,.04)2 (x = 0.3) Single crystals of CuO(Cu,Mg)3[(As0.7P0.3)O4]2 have been prepared by crystallization from melts. The compound crystallizes with triclinic symmetry, space group C '-P l, a = 6.372(4), b = 7.643(7), c = 8.175(5) A, a = 98.59(6), ß = 112.26(3), 7 = 99.03(3)°, Z = 2. CuO(Cu,Mg)3[(Aso)7Po 3)0 4]2 is isotypic to Cu4(P 0 4)20 . X-ray investigations show square planar C u 04 polygons, twisted tetragonal C u 0 5 pyramids, C u 05 bipyramids and elongated (Cu,M g)06 octahedra. | | |
Reference
| (Z. Naturforsch. 51b, 25—28 [1996]; eingegangen am 27. Juli 1995) | | |
Published
| 1996 | | |
Keywords
| Copper, Magnesium, Arsenate, Phosphate, Crystal Structure | | |
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| default:Reihe_B/51/ZNB-1996-51b-0025.pdf | | | Identifier
| ZNB-1996-51b-0025 | | | Volume
| 51 | |
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