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'Phosphane Ligands' in keywords Facet   Publication Year 1998  [X]
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1998[X]
1Author    Dieter Sellmann, Susanne Emig, FrankW. Heinemann, Falk KnochRequires cookie*
 Title    Ubergangsmetallkomplexe mit Schwefelliganden, CXXXIII [1]. Synthese, Struktur und Eigenschaften neuer Fe11-Komplexe mit [FeN2S2]-Gerüsten Transition M etal Complexes with Sulfur Ligands, C X X X III [1]. Synthesis, Structure, and Properties o f N ew F e1 1 Complexes with [ F e N ^ ] Cores  
 Abstract    In order to obtain suitable precursors for iron complexes that model the reactivity o f the active sites o f nitrogenases, the coordination chemistry of the [Fe('N2H2S2')] fragment was systematically investigated('N2 H2S2'2~ = l,2-ethanediamine-N,N'-bis(2-benzenethiolate)(2-)). One-pot reactions o f FeCl2 -4H20 with the tetradentate amine-thiolate ligand 'N2 H2S2'2_ and CO, PR,, or P(O R) 3 yielded the complexes [Fe(CO)2('N 2 H2S2')] (1), [Fe(CO)(PR3)('N 2H2S2')] 
  Reference    Z. Naturforsch. 53b, 1461—1474 (1998); eingegangen am 9. Juli 1998 
  Published    1998 
  Keywords    Iron Sulfur Complexes, Amine Ligands, Phosphane Ligands, X-Ray Data Cyclic Voltammetry 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1461.pdf 
 Identifier    ZNB-1998-53b-1461 
 Volume    53