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'Phenylphosphine' in keywords
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1985 (1)
1Author    PeterG. Jones, HerbertW. Roesky, Hansjörg Grützmacher, GeorgeM. SheldrickRequires cookie*
 Title    Oxidative Knüpfung einer Phosphor-Phosphor-Bindung unter Einwirkung von Ag(I)-bzw. Cu(II)-Ionen: Synthese und Struktur von [(C 6 H5)PH 2 Ag{|i-(C 6 H 5 PH) 2 }]2 (AsF 6 ) 2 , einem sechsgliedrigen Silber-Phosphor-Ring The Oxidative Formation of a Phosphorus-Phosphorus Bond in the Presence of Ag(I) and Cu(II) Ions: Synthesis and Structure of [(C 6 H 5 )PH 2 Ag{^-(C 6 H 5 PH) 2 }] 2 (AsF 6 ) 2 , Containing a Six-Membered Silver-Phosphorus Ring  
 Abstract    The reaction between AgAsF 6 and phenylphosphine proceeds with formation of a phosphorus-phosphorus bond. The main product 1, [(C 6 H 5)PH 2 Ag{u-(C 6 H 5 PH) 2 }] 2 (AsF 6) 2 , was characterized by an X-ray structure determination [PI, a = 919.0(4), b = 1109.8(4), c = 1316.4(5) pm, a = 97.48(3), ß = 107.25(3), y = 102.71(3)°, Z = 1, R = 0.057 for 2806 observed reflections], 1 contains Ag 2 P 4 rings; the silver atoms are further coordinated by phenylphosphine ligands, thus acquiring trigonal coordination geometry. A similar reaction is observed with Cu(AsF 6) 2 , forming the analogous Cu(I) complex 2. 
  Reference    Z. Naturforsch. 40b, 590—593 (1985); eingegangen am 28. Januar 1985 
  Published    1985 
  Keywords    Crystal Structure, Silver, Phenylphosphine, Copper 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0590.pdf 
 Identifier    ZNB-1985-40b-0590 
 Volume    40