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1996 (1)
1Author    Nickolia Lalioti3, JohnM. Tsangaris, ThF. Zafiropoulos, SpyrosP P ErlepesRequires cookie*
 Title    Binding of Cations to 4 f Metal Ions : Preparation and Properties of Lanthanide(III) Complexes Containing the Phenelzinium(l+) Cation as a Ligand  
 Abstract    Treatment o f Ln2(S 0 4)3 • nH 20 (Ln = La, Ce, Pr, Nd, Sm. Eu, Gd ; n -8, 9) with phenelzine dihydrogen sulfate, (phzH2) S 0 4, in 1 N H2S 0 4 yields polymeric complexes with the general formula [L n (S 0 4)2(H 20) 2(phzH)], which contain the phzH+ cation as a ligand. The compounds have been characterized by elem ental analyses, X-ray powder patterns, thermal methods, magnetic susceptibilities and spectroscopic (IR, Raman, electronic diffuse reflec­ tance and solid-state emission f -f spectra) studies. The prepared complexes most probably consist of 7-coordinated units, formed by four bridging bidentate sulfato groups, two terminal aqua m olecules and one cationic phzH+ ligand. 
  Reference    (Z. Naturforsch. 51b, 112 [1996]; received May 19 1995) 
  Published    1996 
  Keywords    Lanthanide(III) Complexes, Phenelzine Dihydrogen Sulfate, Cationic Ligands, IR Spectra 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0112.pdf 
 Identifier    ZNB-1996-51b-0112 
 Volume    51