Go toArchive
Browse byFacets
Bookbag ( 0 )
'Phase Transition' in keywords Facet   section ZfN Section A  [X]
Results  84 Items
Sorted by   
Publication Year
2001 (4)
2000 (19)
1999 (4)
1998 (9)
1997 (5)
1996 (5)
1995 (6)
1994 (10)
1993 (4)
1992 (4)
81Author    L. Guibé, A. Péneau, M. Gourdji, A. PanichRequires cookie*
 Title    Thiourea and Thiourea Inclusion Compounds. A 14 N NQR Investigation  
 Abstract    A reinvestigation of the nitrogen-14 NQR in thiourea has permitted to record, apparently for the first time, the resonances above 169 K. The first order and second order of the transitions at 169 K and 202 K, respectively, appear clearly from the temperature dependence of the resonance frequencies; the mod-ulated structure, incommensurate or commensurate, is also seen on the 14 N NQR spectrum. This study is the first step of a new investigation of thiourea and its inclusion compounds. 
  Reference    Z. Naturforsch. 55a, 331—334 (2000); received October 13 1999 
  Published    2000 
  Keywords    Thiourea, Nitrogen-14 NQR, Phase Transitions, Commensurate, Incommensurate Modu-lations, Inclusion Compounds 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_A/55/ZNA-2000-55a-0331.pdf 
 Identifier    ZNA-2000-55a-0331 
 Volume    55 
82Author    E. Mikuli, A. Migdał-Mikuli, I. Natkanieca, B. GradRequires cookie*
 Title    Phase Transitions and Water Dynamics of [Co(H20 ) 6](C104)2 and [Mn(H20 ) 6](BF4)2 Studied by Neutron Scattering Methods  
 Abstract    Inelastic incoherent neutron scattering (IINS) spectra and neutron powder diffraction (NPD) patterns, registered for [Co(H20) 6](C104)2 at 18 -270 K and for [Mn(H20) 6](BF4)2 at 18 -230 K, provided evidence that these crystals possess three solid phases in these ranges of temperatures. In both compounds the phase transition occurring at T C3 is connected with a change of the crystal structure, and that occurring at T C2 with a change in the rate of the reorientational motions of H20 ligands. 
  Reference    Z. Naturforsch. 56a, 244 (2001); received December 12 2000 
  Published    2001 
  Keywords    Hexaaquacobalt(II) chlorate(VII) and Hexaaquamanganese(II) tetrafluoroborate, Phase Transitions, Structural Changes, Water Reorientation, Neutron Scattering 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0244.pdf 
 Identifier    ZNA-2001-56a-0244 
 Volume    56 
83Author    Albert Würflinger, Denise Mondieig3, Fazil Rajabalee3, MiquelAngel Cuevas-DiartebRequires cookie*
 Title    pVT Measurements and Related Studies on the Binary System /iC16H34 -tiC17H36 and on wC18H38 at High Pressures  
 Abstract    The phase diagram of the binary system nC16H34 -rcC17H36 has been established at ambient pressure using DSC and crystallographic measurements. At low temperatures below the rotator phase RI there exist two crystal forms Op (about jc(C17) = 0.25) and Mdci (about x(C17) = 0.67) which are different from the crystal structures of the pure compounds (Tp for C 16 and Oi for C 17). Furthermore two compositions: (a) C 16/C 17 = 3:1 and (b) = 1:2, which correspond to the coexistence range of Op and Mdci, were chosen for high pressure DTA and pVT measurements, yielding the following findings: The specific volume of the rotator phase of C 17 is distinctly lower than those of the binary systems at the same state point. Assuming the existence of a metastable rotator phase for C 16, an excess volume of A V E/V « 0.01 can be estimated. Due to the very enlarged coexistence range of RI, the mixtures reach their lower transition point at considerably lower temperatures (in isobaric measurements) or higher pressures (in isothermal measurements), where the specific volume is lower than that of C 17 at its transition point. Furthermore, the volume and enthalpy changes of the O ord -RI transition is distinctly smaller for the binary systems than for pure C 17. Thus the specific volumes of the phases Op and Mdci are appreciably larger than t>(spec.) of C 17. Op and Mdci have practically the same specific volume in accordance with the crystallographic results. Enthalpy values are obtained with the aid of the Clausius-Clapeyron equation which agree well with enthalpies derived from the DSC measurements. Furthermore, pVT data have been established for the liquid and solid phases of nC18H38 in the neighbourhood of the melting curve, allowing to determine volume and enthalpy changes of melting as a function of pressure. 
  Reference    Z. Naturforsch. 56a, 626—634 (2001); received July 18 2001 
  Published    2001 
  Keywords    Hexadecane, Heptadecane, Octadecane, pVT, Excess Volume, Phase Transition, High Pressure, X-ray 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0626.pdf 
 Identifier    ZNA-2001-56a-0626 
 Volume    56 
84Author    Y. Kume, T. A. Sajia, R. IkedaRequires cookie*
 Title    Low Temperature Isotope Effect in Ammonium Hexachloroselenate(IV) Studied by 35C1 NQR  
 Abstract    The temperature dependence o f the 35C1 N Q R frequency and spin-lattice relaxation time TlQ of (N H 4)2SeCl6 and (N D 4)2SeCl6 were measured from 400 K to 24.8 and 53.8 K, respectively. The disappearance of N Q R signals in the low temperature region of both salts is attributed to phase transitions. We concluded from the temperature behavior of just above the transition point that the operative mechanism o f the transition is different in these salts: The transition of (N D 4)2SeCl6 seems to be associated with rotary soft modes, while in the natural salt non-rotary soft modes seem to play an important role at the transition. 
  Reference    Z. Naturforsch. 49a, 297 (1994); received August 13 1993 
  Published    1994 
  Keywords    Isotope effect, Spin-lattice relaxation, N Q R, Phase transition, Ammonium hexa­ chloroselenate, Deuterated am m onium hexachloroselenate 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_A/49/ZNA-1994-49a-0297.pdf 
 Identifier    ZNA-1994-49a-0297 
 Volume    49 
Prev
1
2
3
4
5