| 1 | Author | Ernst Guggolz, ManfredL. Ziegler, Willibald Kalcher, Johann Plank, Doris Riedel, WolfgangA. Herrmann | Requires cookie* |
| Title | Synthese und Molekülstruktur der dreikernigen Cluster-Verbindung (^-C5Me5)IrFea(CO)9 Synthesis and Molecular Structure of the Trinuclear Cluster Compound (^ 5 -C5Me5)IrFe2(CO)g  | ||
| Abstract | Reaction of triirondodecacarbonyl (1) with the dinuclear chloroiridium complex [(?? 5 -C5Me5)Ir(//-Cl)Cl]2 (2) in benzene at 50 °C yields the novel mixed iron iridium cluster of composition (rj 5 -C&Mes)IrFe2(C0)9 (8) the molecular structure of which has been established by X-ray diffraction methods. The mononuclear half-sandwich complex (j7 5 -C5Me5)Ir(CO)2 (4) present in the reaction mixture was found to represent the immediate precursor of the cluster compound 8. | ||
| Reference | Z. Naturforsch. 36b, 1053—1059 (1981); eingegangen am 8. April 1981 | ||
| Published | 1981 | ||
| Keywords | Iron, Iridium, Carbonyl Complexes, Pentamethylcyclopentadienyl | ||
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