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'Pentafluorophenyl Derivatives' in keywords Facet   Publication Year 1979  [X]
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1979[X]
1Author    HerbertW. Roesky, Wilfried Schmieder, Klaus AmbrosiusRequires cookie*
 Title    Über Additionsreaktionen von zinnorganischen Verbindungen mit N.N' -Bis(pentafluorphenyl)-sehwefeldiimid Addition Reactions of Tinorganic Compounds with N,N'-Bis(pentafluorophenyl)sulfurdiimide  
 Abstract    The reactions of N,N / -bis(pentafluorophenyl)sulfurdiimide with [(CH3)3Sn]2NCH3, [(CH3)3Sn]3N and [(CHg^SnJaNCeFs yiels the 1:1 adducts 1-3. *H and 19 F NMR investiga-tions show, that fluorine atoms in the ortho position of the phenyl ring coordinate to the tin atom. This causes an increase of electron density at tin. A similar interpretation is given for the adduct 4 of N,N'-bis(^-chlorophenylsulfonyl)sulfurdiimide and [(CH3)3Sn]2NCH3, where an oxygen atom of the sulfonyl group is bonded to tin. 
  Reference    Z. Naturforsch. 34b, 197—199 (1979); eingegangen am 28. September 1978 
  Published    1979 
  Keywords    Pentafluorophenyl Derivatives, Tin, Coordination Compounds 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0197.pdf 
 Identifier    ZNB-1979-34b-0197 
 Volume    34