Go toArchive
Browse byFacets
Bookbag ( 0 )
'Pentacoordination' in keywords
Results  1 Item
Sorted by   
Section
Publication Year
1988 (1)
1Author    FranzA. Mautner, Harald Krischner, Christoph KratkyRequires cookie*
 Title    Darstellung und Kristallstruktur von Zinkazid * 4-Methylpyridin Preparation and Crystal Structure of Zinc Azide * 4-Methylpyridine  
 Abstract    Zinc azide • 4-methylpyridine (1) is formed by the reaction of zinc azide with the corresponding pyridine in aqueous solution. The crystal structure was determined by single crystal X-ray diffrac-tion methods. The crystals of 1 are monoclinic, space group C2/c, Z = 4, a = 1085.5(2), b = 1692.7(11), c = 619.7(6) pm, ß = 113.47(5)°. Each zinc atom is surrounded by five nitrogen atoms (four from azide groups and one from the pyridine adduct) in a distorted trigonal bipyramidal fashion. The ZnN5-polyhedra share common edges to form chains along the crystallographic c-axis. 
  Reference    Z. Naturforsch. 43b, 253—256 (1988); eingegangen am 22. Oktober/3. Dezember 1987 
  Published    1988 
  Keywords    Azide, Crystal Structure, 4-Methylpyridine, Pentacoordination, Zinc 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0253.pdf 
 Identifier    ZNB-1988-43b-0253 
 Volume    43