| | 1 | Author
| Ekkehard Lindner, JuanCarlos Wuhrmann | Requires cookie* | | | Title
| Synthese und Stabilisierung von (Benzoyl-und Pentafluorbenzoyloxy)diphenyIphosphan und Vergleich mit den entsprechenden isomeren Aroyldiphenylphosphanoxiden Synthesis and Stabilization of (Benzoyl-and Pentafluorobenzoyloxy)diphenylphosphane and Comparison with the Corresponding Isomeric Aroyldiphenylphosphane Oxides  | | | | Abstract
| (Benzoyloxy)-and (pentafluorobenzoyloxy)diphenylphosphanes RC(0)0PPh2 (2a, b) [R = C6H5 (a), C6F5 (b)] can be obtained by reaction of ClPPh2 (1) with Na02CC6H5 and Ag02CCeF5, respectively [eq. (1)]. Oxidation of 2a with molecular oxygen yields (benzoyl-oxy)diphenylphosphane oxide (3a) [eq. (2)]. The complexes (0C)5CrPPh20C(0)R (oa, b) are formed by the action of Na2OCC6Hs and Ag02CC6Fs, respectively on (OC)5CrPPh2Cl (4) [eq. (3)]. The chemical and spectroscopical properties of the (aroyloxy)diphenylphosphanes (2 a, b) are compared with the corresponding aryldiphenylphosphane oxides. | | | |
Reference
| Z. Naturforsch. 36b, 297—300 (1981); eingegangen am 28. November 1980 | | | |
Published
| 1981 | | | |
Keywords
| (Pentafluoro)(benzoyloxy)diphenylphosphanes, Pentacarbonylchromium Complexes, IR Spectra, NMR Spectra | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0297.pdf | | | | Identifier
| ZNB-1981-36b-0297 | | | | Volume
| 36 | |
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