| 1 | Author | Beate Dannecker, Gerhard Thiele | Requires cookie* |
| Title | Darstellung und Kristallstruktur von Palladiumoxidchlorid Pd2OCl2 Preparation and Crystal Structure of Palladium Oxide Chloride Pd:OCl2  | ||
| Abstract | Pd2O C l2 was obtained by reaction o f y-PdCl2 and PdO • rcH20 in a K N 0 3/N a N 0 3 melt at 450 °C. Single crystals were grown from a T1C1 flux. The crystal structure o f the tetragonal com pound (a = 631.3(2) pm, c -987.2(2) pm, space group R ^ am d) is built up from bands of edge shared square planar PdO :Cl2 groups connected by com m on O -atom s to a framework. The relationship betw een the structures o f Pd2O Cl2 and PdO is discussed. | ||
| Reference | Z. Naturforsch. 41b, 1363—1366 (1986); eingegangen am 17. Juli 1986 | ||
| Published | 1986 | ||
| Keywords | Palladium O xide Chloride, O xide Chloride, Crystal Structure, Palladium | ||
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