| | 1 | Author
| Heinrich Nöth, Volker Thorn | Requires cookie* | | | Title
| Ligandenstabilisierung durch Komplexbildung: P.P\P''-Triaminocyclotriphosphazan und adamantananaloges Tetraphosphorhexaimid Stabilisation of Ligands by Complex Formation: P,P',P"-Triaminocyclotriphosphazane and an Adamantane-Analogous Tetraphosphorus Hexaimide  | | | | Abstract
| The thermal decomposition of (CO)5MP(NH2)3 (M = Cr, Mo, W) has been studied. No definite products were obtained for M = W but the molybdenum complex yielded [(CO)öMoP]4(NH)6. The same type of complex results with M = Cr, in addition to [(CO)5CrP(NH)NH2]3. The pentacarbonylchromium groups may be removed from the adamantane type [(CO)5CrP]4(NH)e with sulfur. The new compound S4P4(NH)6 results in this reaction. This compound is also a by-product in the thermal decomposition of SP(NH2)3. Attempts to prepare P4(NH)6 by desulfurisation from S4P4(NH)6 or from the chromium complex failed. | | | |
Reference
| Z. Naturforsch. 36b, 1424—1431 (1981); eingegangen am 7. Mai 1981 | | | |
Published
| 1981 | | | |
Keywords
| P, P', P"-Triaminocyclotriphosphazan, Tetraphosphorhexaimid, Tetrathiophosphorylhexaimid | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/36/ZNB-1981-36b-1424.pdf | | | | Identifier
| ZNB-1981-36b-1424 | | | | Volume
| 36 | |
| 2 | Author
| Paraskevas Aslanidis, Joseph Grobe | Requires cookie* | | | Title
| Alternativ-Liganden, XIV [1] Chelating Ligands with CE'Me2 and SiEMe2 Donor Groups | | | | Abstract
| Neue Chelatliganden des Typs (2-Me2E C6H4)Si(EMe2)Me2 (E, E == N, P, As; Me -CH3) Alternative Ligands, XIV [1] Novel Chelating Ligands of the Type (2-Me2E / C6H4)Si(EMe2)Me2 (E, E' = N, P, As; Me = CH3) | | | |
Reference
| Z. Naturforsch. 38b, 280—288 (1983); eingegangen am 27. August/11. November 1982 | | | |
Published
| 1983 | | | |
Keywords
| (E, E' = N, P, As); Synthesis, Spectroscopic Characterization (NMR, IR, MS) | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/38/ZNB-1983-38b-0280.pdf | | | | Identifier
| ZNB-1983-38b-0280 | | | | Volume
| 38 | |
| 3 | Author
| NarendraS. Sridhara | Requires cookie* | | | Title
| Thermal Decomposition of P,P-diphenyl-N-benzyl-phosphinothioic Amide and P,P-diphenyl-N-methyl-phosphinothioic Amide | | | |
Reference
| Z. Naturforsch. 33b, 212—213 (1978); received July 1 1977 | | | |
Published
| 1978 | | | |
Keywords
| 2, 2, 4, 4, 6, 6-Hexaphenylcyclophosphazatriene, Diphenylphosphinothioic Amide, 113355-Hexaphenyl-1 -methylaminotriphosphazene-5-sulphide, P, P-Diphenyl-N-dimethylphosphinothioic Amide | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/33/ZNB-1978-33b-0212.pdf | | | | Identifier
| ZNB-1978-33b-0212 | | | | Volume
| 33 | |
|
