| | 1 | Author
| Uwe Klingebiel, Norbert Vater, William Clegg, Martin Haase, GeorgeM. Sheldrick | Requires cookie* | | | Title
| Synthesis of Silicon-Phosphorus-Rings - Structure of a cis-2,2,4,4-Tetrakis(silylamino)-l,3-diphospha-2,4-disilacyclobutane  | | | | Abstract
| Fluorosilylphosphanes of the type R2SiFPHR' (R = CHMe2, CMe3, NMeSiMe3; R' = H, C6H5; 1-4) are obtained in the reaction of difluorosilanes with lithiated phosphanes in a molar ratio 1:1. Diphosphasilanes (5, 6) and a difluorosilylphosphane (7) are isolated as by-products. 1-4 react with w-QjHgLi to give cyclic silylphosphanes, LiF, and C4H10 (8-11). Dilithiated 5 reacts with F2PN(CMe3)SiMe3 to form of a four-membered SiP3-ring 12. The 31 P NMR spectra of 9 and 11 show signal coalescence for the eis-and tfrans-isomers at room temperature. The crystal structure of the cis-isomer of 11 has been determined. The substituted ring 13 is prepared in the reaction of lithiated 9 and Me2SiF2. | | | |
Reference
| Z. Naturforsch. 38b, 1557—1562 (1983); eingegangen am 6. Juli 1983 | | | |
Published
| 1983 | | | |
Keywords
| Fluorosilylphosphanes, Cyclisation, P-Inversion, Isomers, Crystal Structure | | | |
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| default:Reihe_B/38/ZNB-1983-38b-1557.pdf | | | | Identifier
| ZNB-1983-38b-1557 | | | | Volume
| 38 | |
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