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1978 (1)
1Author    Gerd-Volker RöschenthalerRequires cookie*
 Title    Über die Reaktionen von Phosphanen MenP [OCH(CF3 )2] 3_" mit Hexafluoraceton Reactions of Phosphanes MenP[OCH(CF3)2]3-n with Hexafluoroacetone  
 Abstract    The stable phosphanes Me2POCH(CF3)2 and MeP[OCH(CF3)2]2 have been prepared and reacted with hexafluoroacetone yielding 1,2-oxaphosphetanes. The analogous reaction with Me2PF was carried out giving a 1 : 1 : 1 mixture of a 1,3,2-, a 1,3,4-dioxaphospholane, and a 1,2-oxaphosphetane. P[OCH(CF3)2]3 did not react with hexafluoroacetone. The new compounds were characterized by NMR, mass spectrometry and elemental analysis. 
  Reference    Z. Naturforsch. 33b, 131—135 (1978); eingegangen am 12. September 1977 
  Published    1978 
  Keywords    Dimethylhexafluoroisopropoxyphosphane, Methyl-bis(hexafluoroisopropoxy)phosphane, 1, 2-Oxaphosphetanes, Oxyphosphoranes, Hexafluoroacetone 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0131.pdf 
 Identifier    ZNB-1978-33b-0131 
 Volume    33