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'Oxopentafluorovanadates V' in keywords
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1976 (1)
1Author    Helmut Rieskamp, Rainer MattesRequires cookie*
 Title    Fluorreiche Oxofluorovanadate(V): Die Kristallstruktur von [enH2] [VOF5]  
 Abstract    The crystal structure of triclinic [enH2][VOF5], prepared in aqueous solution, has been determined from X-ray diffractometer data (i? = 0.076 for 527 reflections). The structure contains monomeric [VOFs] 2--ions. The bond distances are 1.54(1) Ä (terminal oxygen), 1.80(1) (average for the cis-fluorine atoms) and 2.10(1) Ä for the fluorine atom in trans-position to the terminal oxygen atom. This fluorine atom is involved in strong hydrogen bonds originating from the [NHaCH^CH^NEy 2 " 1 -cation with cisoid conformation. Earlier results about the existence of K2VOF5 could not be confirmed. 
  Reference    (Z. Naturforsch. 31b, 1453—1455 [1976]; eingegangen am 2. August 1976) 
  Published    1976 
  Keywords    Oxopentafluorovanadates(V), Crystal Structure, Vibrational Spectra 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-1453.pdf 
 Identifier    ZNB-1976-31b-1453 
 Volume    31