1 | Author | Carola Stoll, Ingo-Peter Lorenz, Heinrich Nöth, Thomas Seifert | Requires cookie* |
Title | Oxochlorierung von Ubergangsmetall-Komplexen mit Thionylchlorid Oxochlorination of Transition Metal Complexes with Thionyl Chloride ![]() | ||
Abstract | The reaction of the transition metal complexes CpV(CO)4 and [CpM o(CO)3]2 with thionyl chloride affords the oxodichlorides C pM (0)C l2 (M = V, Mo) by oxidative decarbonylation. The X-ray structure analysis of C pV (0)C l2 shows the pseudo tetrahedral "piano-stool" configuration for the central vanadium atom. E in le itu n g | ||
Reference | Z. Naturforsch. 53b, 153—156 (1998); eingegangen am 25. November 1997 | ||
Published | 1998 | ||
Keywords | Thionyl Chloride, Oxochlorination, Metaloxodichloride, X-Ray Data | ||
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