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1988[X]
1Author    Wolfgang Weigand, Ulrich Nagel, Wolfgang BeckRequires cookie*
 Title    Pseudohalogeno-Metallverbindungen, LXVIII [1] Reaktionen der Cyanometallsäuren NCAuCNH  
 Abstract    , (NC) 4 Pt(CNH) 2 , (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) undCo[bis(dimethyIglyoximato)](CN)CNHmit Epoxiden: 2-Hydroxyalkylisocyanid-und Oxazolidin-2-yIiden-MetalIkomplexe Pseudohalogeno Metal Compounds, LXVIII [1] Reaction of Cyano Metal Acids NCAuCNH, (NC) 4 Pt(CNH) 2 , (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) and Co[bis(dimethylglyoximato)](CN)CNH with Epoxides: 2-Hydroxyalkylisocyanide and Oxazolidine-2-ylidene Metal Complexes NCAuCNH reacts with expoxides to give oxazolidine-2-ylidene (2) and 2-hydroxyalkyl com-plexes (3), respectively. Complexes with cyclic carbene ligands (NC) 4 Pt(-C-O —C—C-NH) 2 (5) and (NC)(Hdmg) 2 Co-C-O-C-C-NH (7) are formed from the corresponding isocyanic metal compounds and oxiranes. 5b has been characterized by crystal structure determination. Ring opening of phenyloxirane occurs at the phenyl substituted carbon atom. (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) and oxirane yield mixtures of (NC) 2 M(—CN—C—C—OH) 4 and (NC) 2 M[—CN—C—C—(—O—C—C—)"—O—C—C—OH] 4 . 
  Reference    Z. Naturforsch. 43b, 328—338 (1988); eingegangen am 6. November 1987 
  Published    1988 
  Keywords    Ruthenium, Osmium, Cobalt Complexes of Isocyanic, 2-Hydroxyalkylisocyanide, Cyclic Aminooxycarbene 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0328.pdf 
 Identifier    ZNB-1988-43b-0328 
 Volume    43