| | 2 | Author
| Helmut Behrens, Anton Jungbauer | Requires cookie* | | | Title
| Über die Reaktionen von ein-und zweikernigen, kationischen ?/ 5 -Cyelopentadienyl-carbonyl-Komplexeii des Eisens, Rutheniums und Osmiums mit flüssigem Ammoniak [1] On the Reactions of Mono-and Dinuclear, Cationic ^-Cyclopentadienyl Carbonyl Complexes of Iron, Ruthenium and Osmium with Liquid Ammonia [1]  | | | | Abstract
| The covalent carbamoyl compounds 7?5.c5H5Ru(CO)(L)(CONH2) (L = CO, MeCN, MeNC, PPh3, PEt3) and ^-CsHsOsfCOMCONI^) are formed by the reactions of the cationic complexes [7?5.C5H5Ru(CO)2(L)]+ (L = CO, MeCN, MeNC, PPh3, PEt3) and [^ 5 -C5H5Os(CO)3]+ with liquid NH3 below 10 °C. In contrast, the reaction of [^ 5 -C5H5Ru(CO)2(r? 2 -C2H4)]PF6 with liquid NH3 yields the quarternary ammonium salt | | | |
Reference
| Z. Naturforsch. 34b, 1477—1486 (1979); eingegangen am 3. August 1979 | | | |
Published
| 1979 | | | |
Keywords
| ^-Cyclopentadienyl Carbamoyl Carbonyl Complexes, Iron, Ruthenium, Osmium | | | |
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| default:Reihe_B/34/ZNB-1979-34b-1477.pdf | | | | Identifier
| ZNB-1979-34b-1477 | | | | Volume
| 34 | |
| 3 | Author
| Organometallic Lewis, Philipp Rosendorfer, Shahram Mihan, Burkhard Niemer, Wolfgang Beck | Requires cookie* | | | Title
| Metallorganische Lewis-Säuren, LV [1] Darstellung und Reaktionen von Tetracarbonylmethyltetrafluoroboratoosmium, cis-( OC)4Os(FBF3)CH3 | | | | Abstract
| Acids, LV [1] Preparation and Reactions of Tetracarbonylmethyltetrafluoroboratoosm ium , cis-(O C)4Os(FBF3)CH3 The reaction of ds-M e2O s(C O)4 with H BF4 Et20 affords the complex cis-(O C)4O s(FBF3)CH3 (2). The coordinated tetrafluoroborate of 2 is easily substituted by H70 , [R e(C O)5] \ [R e(C O)4(C N)CH 3]-(from R e(C O)5CH3 and N aN (SiM e3)2), SC N ' and PPhMe2 | | | |
Reference
| Z. Naturforsch. 50b, 1759—1766 (1995); eingegangen am 3. April 1995 | | | |
Published
| 1995 | | | |
Keywords
| Osmium, Rhenium, Metal Carbonyl, Tetrafluoroborate, Methyl | | | |
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| default:Reihe_B/50/ZNB-1995-50b-1759.pdf | | | | Identifier
| ZNB-1995-50b-1759 | | | | Volume
| 50 | |
| 5 | Author
| Wolfgang Weigand, Ulrich Nagel, Wolfgang Beck | Requires cookie* | | | Title
| Pseudohalogeno-Metallverbindungen, LXVIII [1] Reaktionen der Cyanometallsäuren NCAuCNH | | | | Abstract
| , (NC) 4 Pt(CNH) 2 , (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) undCo[bis(dimethyIglyoximato)](CN)CNHmit Epoxiden: 2-Hydroxyalkylisocyanid-und Oxazolidin-2-yIiden-MetalIkomplexe Pseudohalogeno Metal Compounds, LXVIII [1] Reaction of Cyano Metal Acids NCAuCNH, (NC) 4 Pt(CNH) 2 , (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) and Co[bis(dimethylglyoximato)](CN)CNH with Epoxides: 2-Hydroxyalkylisocyanide and Oxazolidine-2-ylidene Metal Complexes NCAuCNH reacts with expoxides to give oxazolidine-2-ylidene (2) and 2-hydroxyalkyl com-plexes (3), respectively. Complexes with cyclic carbene ligands (NC) 4 Pt(-C-O —C—C-NH) 2 (5) and (NC)(Hdmg) 2 Co-C-O-C-C-NH (7) are formed from the corresponding isocyanic metal compounds and oxiranes. 5b has been characterized by crystal structure determination. Ring opening of phenyloxirane occurs at the phenyl substituted carbon atom. (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) and oxirane yield mixtures of (NC) 2 M(—CN—C—C—OH) 4 and (NC) 2 M[—CN—C—C—(—O—C—C—)"—O—C—C—OH] 4 . | | | |
Reference
| Z. Naturforsch. 43b, 328—338 (1988); eingegangen am 6. November 1987 | | | |
Published
| 1988 | | | |
Keywords
| Ruthenium, Osmium, Cobalt Complexes of Isocyanic, 2-Hydroxyalkylisocyanide, Cyclic Aminooxycarbene | | | |
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| default:Reihe_B/43/ZNB-1988-43b-0328.pdf | | | | Identifier
| ZNB-1988-43b-0328 | | | | Volume
| 43 | |
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