| 1 | Author
| G. C. Papavassiliou, D. Layek | Requires cookie* | | Title
| Electronic and Resonance Raman Spectra of Some New Mixed-Valence Compounds of Pt and Pd with a Metal-Halide Chain  | | | Abstract
| The electronic and resonance Raman spectra of new mixed-valence compounds of the type M2'[M(L)X3][M(L)X5], where M' = K, NH4, M -Pt or Pd, L = NH3 or pyridine, and X = Cl, Br or I, have been studied. The single-crystal polarized reflectance spectra indicate the one-dimensional semiconductor behaviour. The polarized resonance Raman spectra confirm the —M(II)—X-M(IV)-X linear chain structure, which is in accordance with the X-ray results. The polarization of M-N bands can be explained by the Snyder's theory (1971). | | |
Reference
| Z. Naturforsch. 35b, 676—679 (1980); received January 14 1980 | | |
Published
| 1980 | | |
Keywords
| Electronic Spectra, Raman Spectra, Mixed-Valence, Oriented Molecules | | |
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| default:Reihe_B/35/ZNB-1980-35b-0676.pdf | | | Identifier
| ZNB-1980-35b-0676 | | | Volume
| 35 | |
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