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1992 (1)
1Author    Feng-Quan Liu, Hans-Georg Schmidt, M. Athias Noltemeyer, Cristina Freire-Erdbrügger, GeorgeM. Sheldrick, HerbertW. RoeskyRequires cookie*
 Title    Synthesis and Structure of Eight-Membered Titanium Containing Siloxane Rings  
 Abstract    The preparation by different methods o f the eight-membered ring com pounds (R 'X T i0S iR 220) 2 is reported: (2: R' = C5H 5, X=C1, R2=/Bu; 3: R '= N (S iM e3)2, X=C1, R 2=/Bu; 4: R' = C 5M e5, X = C1, R 2=Ph; 6: R' = X = N E t2, R 2=fB u). The six-membered ring Ph2SiO[OTiC5M e5(Cl)]2 5 is formed together with 4 by the reaction o f C5M e5TiCl3 and Ph2Si(OLi)2. Com pounds 2 and 4 have been characterized by X-ray structural analysis. 
  Reference    Z. Naturforsch. 47b, 1085—1090 (1992); received March 2 1992 
  Published    1992 
  Keywords    Organotitanium, Amides, Siloxanes, Eight-Membered Rings 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-1085.pdf 
 Identifier    ZNB-1992-47b-1085 
 Volume    47