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'Organometallic Compounds' in keywords Facet   Publication Year 1982  [X]
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1982[X]
1Author    Lutz Dahlenburg, Fazlollah Mirzaei, Ah YardimciogluRequires cookie*
 Title    Alkyl-und Arylkomplexe des Iridiums und Rhodiums  
 Abstract    , IX [1] Organorhodiumverbindungen Rh(R)(CO)(PPh3)2 (R = Alkyl, Aryl) und homologe Iridiumalkyle Alkyl and Aryl Complexes of Iridium and Rhodium, IX [1] Organorhodium Compounds Rh(R)(CO)(PPh3)2 (R = Alkyl, Aryl) and Related Iridium Alkyls A series of organorhodium and -iridium complexes M(R)(CO)(PPh 3)2 (M = Rh: R = CeHs, 2-MeC6H4, 4-MeC6H4, 2,4,6-Me3C6H2, CH3, CH2SiMe3, CH2CMe3; M = Ir: R = CH3, CH2Ph, CH2SiMe3, CH2CMe3) has been prepared from MCl(CO)(PPh3)2 and the correspond-ing organolithium or Grignard reagents. Of these compounds, the mesitylrhodium complex Rh(2,4,6-Me3C6H2)(CO)(PPh3)2 as well as the iridium and rhodium alkyls with Me3SiCH2 and Me3CCH2 ligands show cis,irans-isomerism which is demonstrated on the basis of infrared and NMR spectroscopic evidence. 
  Reference    Z. Naturforsch. 37b, 310—317 (1982); eingegangen am 23. Oktober 1981 
  Published    1982 
  Keywords    Rhodium, Iridium, Organometallic Compounds, eis, frarw-Isomerism, NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0310.pdf 
 Identifier    ZNB-1982-37b-0310 
 Volume    37