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'Organoiron Complexes' in keywords Facet   section ZfN Section B  [X]
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1981 (1)
1Author    EricaL. Weinberg, J.Thomas Burton, MichaelC. Baird, Max HerberholdRequires cookie*
 Title    A Novel Isomerization of an Electron-Rich Alkene  
 Abstract    Displacement of 2-methvlpropene from [Fp(Me2C = CH2)]BF4 (Fp = (/?5-C5H5)Fe(CO)2) by Z-1,2-dimethoxyethylene (Z-DME) gives [Fp(Z-DME)]BF4. Displacement by E-1,2-dimethoxyethylene (E-DME), in contrast, does not give the expected complex of E-DME, but rather the complex of the Z-alkene. A mechanism involving scission of the C = C bond of the coordinated alkene to give a bis-carbene intermediate is proposed. 
  Reference    Z. Naturforsch. 36b, 485—487 (1981); received February 9 1981 
  Published    1981 
  Keywords    Organoiron Complexes, Olefin Isomerization, 1, 2-Dimethoxyethylene 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0485.pdf 
 Identifier    ZNB-1981-36b-0485 
 Volume    36