| | 1 | Author
| EricaL. Weinberg, J.Thomas Burton, MichaelC. Baird, Max Herberhold | Requires cookie* | | | Title
| A Novel Isomerization of an Electron-Rich Alkene  | | | | Abstract
| Displacement of 2-methvlpropene from [Fp(Me2C = CH2)]BF4 (Fp = (/?5-C5H5)Fe(CO)2) by Z-1,2-dimethoxyethylene (Z-DME) gives [Fp(Z-DME)]BF4. Displacement by E-1,2-dimethoxyethylene (E-DME), in contrast, does not give the expected complex of E-DME, but rather the complex of the Z-alkene. A mechanism involving scission of the C = C bond of the coordinated alkene to give a bis-carbene intermediate is proposed. | | | |
Reference
| Z. Naturforsch. 36b, 485—487 (1981); received February 9 1981 | | | |
Published
| 1981 | | | |
Keywords
| Organoiron Complexes, Olefin Isomerization, 1, 2-Dimethoxyethylene | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0485.pdf | | | | Identifier
| ZNB-1981-36b-0485 | | | | Volume
| 36 | |
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