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'Organocyclotriarsane pentacarbonylchromium Complex' in keywords
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1978 (1)
1Author    Jochen Ellermann, HelmutA. Lindner, Horst Schössner, Gerhard Thiele, Gerd ZoubekRequires cookie*
 Title    Chemie poly funktioneller Liganden, 48 [1] Synthese, Schwingungsspektren, Molekül-und Kristallstruktur eines Organocyclotriarsan-pentacarbonylchrom-Komplexes Chemistry of Polvfunctional Ligands, 48 [1] Synthesis, Vibrational Spectra, Molecular and Crystal Structure of an Organocyclotriarsane-pentacarbonylchromium Complex  
 Abstract    The organocyclotriarsane, CH3C(CH2As)3 (1), reacts with chromium hexacarbonyl on ultraviolet irradiation to give the complex CH3C(CH2As)3Cr(CO)5 (2), in which the cyclo-triarsane is behaving as a monodentate ligand. The crystal structure of 2 has been determinated by X-ray diffraction. The monoclinic unit cell (space group P2i/n) contains 4 isolated molecules in a hexagonal closest packing. The mass spectrum of 2 shows the parent peak and clear fragmentation patterns. The infrared and Raman spectra are reported for 1 and 2 in the 3000-30 cm -1 region. Most of the fundamental vibrations are assigned. 
  Reference    Z. Naturforsch. 33b, 1386—1392 (1978); eingegangen am 10. Oktober 1978 
  Published    1978 
  Keywords    Organocyclotriarsane-pentacarbonylchromium Complex, Vibrational Spectra, Crystal Structure, Molecular Structure 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1386.pdf 
 Identifier    ZNB-1978-33b-1386 
 Volume    33