| | 1 | Author
| Hristoph Linke, M. Artin, Jansen | Requires cookie* | | | Title
| C  | | | | Abstract
| Ag8Ge3O 10 was obtained from a mixture of the binary oxides by solid state reaction in the presence of a small amount of water which is acting as an accelerator. Conditions applied were T = 500 °C and p (0 2) = 1,2 kbar. According to an X-ray crystal structure analysis the title compound contains four crystallographically independent trigermanate [Ge3O 10]8-ions per unit cell (Pc, a = 12.1549(11), b = 10.7375(14), c = 18.5169(20) Ä, ß = 92.326(10)°, 13448 independent reflections, R 1 = 6 ,1 %, wR2 = 13,0%, Z = 8). Thermal decomposition, as recorded by DTA and temperature dependent Guinier photographs, occurs at 520 °C. Ag8Ge3O ,0 is diamagnetic with a molar susceptibility of -330-10" cm3 mol" 1. Darstellung, Kristallstruktur und physikalische Eigenschaften von Oktasilbertrigermanat, Ag8Ge3O10 | | | |
Reference
| Z. Naturforsch. 51b, 1591—1597 (1996); eingegangen am 18. April 1996 | | | |
Published
| 1996 | | | |
Keywords
| Octasilver Trigermanate, High Oxygen Pressure Synthesis, Crystal Structure, Physical Properties | | | |
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| default:Reihe_B/51/ZNB-1996-51b-1591.pdf | | | | Identifier
| ZNB-1996-51b-1591 | | | | Volume
| 51 | |
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