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'O Borylhydroxylamines' in keywords Facet   Publication Year 1980  [X]
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1980[X]
1Author    Peter Paetzold, Günther SchimmelRequires cookie*
 Title    ungesättigter Stickstoffbasen Boration Reactions with the N-Oxides and m-Imines of Unsaturated Nitrogen Bases  
 Abstract    -Dipolar reagents with an unsaturated CNO-or CNN-skeleton undergo 1,3-organo-boration by triorganoboranes. On the other hand, the unsaturated NNO-skeletons in azoxybenzene or nitrous-oxide are reduced to the corresponding NN-fragment by trialkyl-boranes. The 1,3-addition of aminoborane Cl2BNMe2 to the aldimineoxide PhHC = NMe-0 represents one of the rare examples of analogous reactivity of BN-and CC-double bonds. O-Borylhydroxylamines PhHCR-NMe-OBR2 are reduced by BR'3 to PhHCR-NMe-BR'2 and R'0-BR2. Similar reduction products are isolated from liquid-phase thermolysis of PhHCEt-NMe-OBEt2 (16), whereas gas-phase thermolysis of 16 gives PhCH = NMe, (EtBO)3, and C4HI0. 
  Reference    Z. Naturforsch. 35b, 568—577 (1980); eingegangen am 6. Dezember 1979 
  Published    1980 
  Keywords    O-Borylhydroxylamines, Borylhydrazines, 2-Borylhydrazones, Organoboration, Aminoboration 1, 3 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0568.pdf 
 Identifier    ZNB-1980-35b-0568 
 Volume    35