| | 1 | Author
| Z. Naturforsch | Requires cookie* | | | Title
| Synthese und Charakterisierung von 1,3,5-Hexahydrotriazin-Komplexen des Mo° und Movl  | | | | Abstract
| Organo-substituted 1,3,5-hexahydrotriazine com plexes of the type (R N C H 2)3M o(C O)3 (R = CFI3, / -C 3 H 7 and CH2C6H 5) are obtained by ligand displacement from 7 6-C7H 8M o(C O)3 in high yields. These products have been characterized by 'H. 13C, 95Mo NM R, IR as well as mass spectroscopy and contain an electron-rich M o(C O)3 center bonded to the 1,3,5-hexahydrotriazine 6 e donor via three M o -N bonds. Oxidation o f the Mo° com plex l,3,5-(C H 3N CH 2)3M o(C O)3 with H20 2 under carefully controlled conditions allows iso lation of 1,3,5-(CH3N C H 2) 3M o 0 3 containing a M ovl center. Chemical and spectroscopic properties o f these com plexes are compared with those o f related Mo com plexes with neutral macrocyclic ligands containing N 3 donor sets. | | | |
Reference
| Z. Naturforsch. 50b, 1038—1044 (1995); eingegangen am 30. Dezem ber 1994 | | | |
Published
| 1995 | | | |
Keywords
| 1, 3, 5-Hexahydrotriazines, Carbonyl Complexes, O xo Complexes, R edox Chemistry, Multinuclear NM R Spectra | | | |
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| default:Reihe_B/50/ZNB-1995-50b-1038.pdf | | | | Identifier
| ZNB-1995-50b-1038 | | | | Volume
| 50 | |
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