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'O xo Complexes' in keywords Facet   Publication Year 1995  [X]
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1995[X]
1Author    Z. NaturforschRequires cookie*
 Title    Synthese und Charakterisierung von 1,3,5-Hexahydrotriazin-Komplexen des Mo° und Movl  
 Abstract    Organo-substituted 1,3,5-hexahydrotriazine com plexes of the type (R N C H 2)3M o(C O)3 (R = CFI3, / -C 3 H 7 and CH2C6H 5) are obtained by ligand displacement from 7 6-C7H 8M o(C O)3 in high yields. These products have been characterized by 'H. 13C, 95Mo NM R, IR as well as mass spectroscopy and contain an electron-rich M o(C O)3 center bonded to the 1,3,5-hexahydrotriazine 6 e donor via three M o -N bonds. Oxidation o f the Mo° com ­ plex l,3,5-(C H 3N CH 2)3M o(C O)3 with H20 2 under carefully controlled conditions allows iso­ lation of 1,3,5-(CH3N C H 2) 3M o 0 3 containing a M ovl center. Chemical and spectroscopic properties o f these com plexes are compared with those o f related Mo com plexes with neutral macrocyclic ligands containing N 3 donor sets. 
  Reference    Z. Naturforsch. 50b, 1038—1044 (1995); eingegangen am 30. Dezem ber 1994 
  Published    1995 
  Keywords    1, 3, 5-Hexahydrotriazines, Carbonyl Complexes, O xo Complexes, R edox Chemistry, Multinuclear NM R Spectra 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1038.pdf 
 Identifier    ZNB-1995-50b-1038 
 Volume    50