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1992 (1)
1Author    Hiroshi Ohki, Nobuo NakamuraRequires cookie*
 Title    Sodium Ion Exchange in Na 1+x Zr 2 Si x P 3 _ ;c 0 1 2 as Studied by 23 Na Nutation NMR  
 Abstract    23 Na two-dimensional nutation NMR was applied to Nat + *Zr2SivP3_vO,2 with x = 0, 1, and 2. The nutation spectrum in each compound consists of two clearly separated peaks corresponding to the two crystallographically inequivalent sodium sites. In the compound with x = 2 the nuclear quadrupole coupling constants (e Qq/h) and the asymmetry parameters (rj) were by spectral simu-lation estimated to be 1.0 MHz and 0 for one site, and 1.5 MHz and 0.8 for the other site. The spectrum varies considerably on heating; the two peaks merge into a single peak at high tempera-tures due to fast ion exchange between the two different sites. For x = 0 and x = 1 the nutation spectra did not show any significant temperature dependence, suggesting that the rates of the sodium ion exchange are negligibly low. 
  Reference    Z. Naturforsch. 47a, 319—324 (1992); received August 10 1991 
  Published    1992 
  Keywords    Nutation NMR, Quadrupole effect, Superionic conductor, Chemical exchange 
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 TEI-XML for    default:Reihe_A/47/ZNA-1992-47a-0319.pdf 
 Identifier    ZNA-1992-47a-0319 
 Volume    47