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'Nucleophilicity' in keywords Facet   Publication Year 1975  [X]
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1975[X]
1Author    J., D. K.Requires cookie*
 Title    S 0 2-Einschiebung in Triphenylvinylzinn D eterm ination of the Nucleophilicity of Tin-Carbon Bond, I I 1 S 0 2-Insertion into Triphenylvinyltin  
 Abstract    The S 0 2-insertion into tin-carbon bonds of mixed tetraorganostannanes, R 3SnR / (R = C6H 5, CH3; R' = CH3, C6H 5, CH2 = CH), is determined by the nucleophilicity of the organic residue attached to metal and shows a decreasing rate in the order aryl > alkenyl > alkyl. A correlation to Taft's constant is given. The behaviour of triphenylvinyltin toward sulfur dioxide is in good agreement with this S 0 2 takes place only into Sn-C6H 5 bond. 
  Reference    (Z. Naturforsch. 30b, 91—95 [1975]; eingegangen am 24. September 1974) 
  Published    1975 
  Keywords    Nucleophilicity, Tin-carbon Bond, S 0 2-insertion, Triphenylvinyltin, Taft's Constant 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0091.pdf 
 Identifier    ZNB-1975-30b-0091 
 Volume    30