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'Non Metal Stabilized Carbenes' in keywords
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1989 (1)
1Author    W. Olf, Peter Fehlhammer, Hans Hoffmeister, Borislav Boyadjiev, Thomas KolrepRequires cookie*
 Title    Bor-stabilisierte N,0-Carbene, II [1] Röntgenstrukturanalyse von (fra/i5-4,5-Dimethyloxazolidin-2-yliden)triphenylbor und N-Alkylierungen Boron Stabilized N,0-Carbenes, II [1] X-Ray Structure of (/rans-4,5-Dimethyloxazolidin-2-ylidene)triphenylboron and N-Alkylations  
 Abstract    The X-ray structure analysis of (?rartj,-4,5-dimethyloxazolidin-2-ylidene)triphenylboron reveals a stereochemistry of the carbene ligand which is almost identical with that in transition metal complexes. Deprotonation of triphenylboron stabilized oxazolidin-2-ylidenes with NaH leads to (oxazolin-2-ato)borates, which have been N-alkylated with [R30 +][BF4_] or R I under mild condi­ tions. 
  Reference    Z. Naturforsch. 44b, 917 (1989); eingegangen am 27. Dezember 1988/8. März 1989 
  Published    1989 
  Keywords    Non-Metal Stabilized Carbenes, Reactions at Coordinated Ligands, X-Ray Structure 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0917.pdf 
 Identifier    ZNB-1989-44b-0917 
 Volume    44