Go toArchive
Browse byFacets
Bookbag ( 0 )
'Nitrosyltransfer' in keywords Facet   Publication Year 1987  [X]
Results  1 Item
Sorted by   
Section
Publication Year
1987[X]
1Author    Anke Brauel, Dieter RehderRequires cookie*
 Title    Ein neuer Weg zur Darstellung der Nitrosylkomplexe CpM(CO) 2 NO (M = Cr/Mo/(W)) durch NO/CO-Austausch zwischen [Co(NO) 2 Hal] 2 und Carbonyl-cyclopentadienylkomplexen* A Novel Route to the Nitrosyl Complexes CpM(CO) 2 NO (M = Cr/Mo/(W)) by NO/CO Exchange between [Co(NO) 2 Hal] 2 and Carbonyl-cyclopentadienyl Complexes  
 Abstract    The title compounds have been prepared by NO transfer from [Co(NO)iHal] 2 (Hal = Cl, Br, I) to [CpM(CO) 3 ] 2 , CpM(H)(CO) 3 and [CpM(CO) 3 ]" (M = Cr, Mo, W; Cp = ?7 5 -C 5 H 5). In the case of the neutral complexes, the reactions need initiation and support by light; the anionic complexes are nitrosylated in a dark reaction. The highest yields (60%) are obtained from the reactions between [Co(NO) 2 Br] 2 and [CpM(CO) 3 ] 2 (M = Cr, Mo). 
  Reference    Z. Naturforsch. 42b, 605—609 (1987); eingegangen am 26. November 1986/7. Januar 1987 
  Published    1987 
  Keywords    Nitrosyltransfer, Carbonyl-Nitrosyl Complexes, Chromium, Molybdenum, Tungsten 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0605.pdf 
 Identifier    ZNB-1987-42b-0605 
 Volume    42