| 1 | Author | Michael Witt, HerbertW. Roesky, Mathias Noltemeyer, GeorgeM. Sheldrick | Requires cookie* |
| Title | Synthese und Struktur von H 2 NS0 2 NWC1 4 - ein Kirsanov-Reagens mit einem Übergangsmetallatom Synthesis and Structure of H 2 NS0 2 NWC1 4 - a Kirsanov Reagent with a Transition Metal Atom  | ||
| Abstract | H 2 N-S0 2 -NWC1 4 (1) has been synthesized from WC1 6 and S0 2 (NH 2) 2 , and forms adducts with donor solvents such as pyridine and acetonitrile. 1CH 3 CN crystallizes in the space group P2,/n with cell constants a = 652.5(1); b = 2325.3(2); c = 775.8(1) pm; ß = 90.32(1)°. The nitrogen-tungsten bond length of 173.0 pm and the S—N—W bond angle of 169.3° indicate a W=N double bond. | ||
| Reference | Z. Naturforsch. 42b, 519—521 (1987); eingegangen am 1. Dezember 1986/20. Januar 1987 | ||
| Published | 1987 | ||
| Keywords | Crystal Structure, Sulfamide, Nitrogen-Tungsten Double Bond | ||
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