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'Nitridophthalocyaninatomanganese V' in keywords
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1990 (1)
1Author    Horst Grünewald, Heiner HomborgRequires cookie*
 Title    Darstellung und spektroskopische Charakterisierung von Nitridophthalocyaninatomangan(V) Preparation and Spectroscopical Characterization of Nitridophthalocyaninatom anganese(V)  
 Abstract    Nitridophthalocyaninatomanganese(V), M nN Pc(2-), has been prepared by oxidation of [Mn(OH):Pc(2-)]~ with chlorine in the presence of excess ammonia in dichloromethane as a chemically very stable, diamagnetic microcrystalline blue powder. The band at 1053 cm 1 in the infrared and resonance Raman spectra is assigned to v(Mn=N). The strong resonance en­ hancement of v(Mn=N) coincides with an electronic transition at 461 nm assigned to (N —> Mn) electron transfer. The UV-VIS spectrum in 1-chloronaphthalene is compared with that of the M nN Pc(2-)-H -,S04 adduct and the phthalocyanine-7r-cation radical [MnNPc(l -) ] +. 
  Reference    Z. Naturforsch. 45b, 483—489 (1990); eingegangen am 30. November 1989 
  Published    1990 
  Keywords    Nitridophthalocyaninatomanganese(V), IR Spectra, Resonance Raman Spectra, UV-VIS Spectra 
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 TEI-XML for    default:Reihe_B/45/ZNB-1990-45b-0483.pdf 
 Identifier    ZNB-1990-45b-0483 
 Volume    45