| | 1 | Author
| M. Ludwig3, R. Niewab, R. Kniep | Requires cookie* | | | Title
| Dimers [A12N6]12-and Chains J j A lN ^ ] in the Crystal Structures of Ca6[Al2N6] and Ba3[Al2N4]  | | | | Abstract
| Pale yellow transparent single crystals of Ca6[Al2Nö] (P 2\/c, No. 14, a = 693.7(3), b = 614.9(3), c = 987.1(5) pm, ß = 94.01(5)°; Z = 4) and colourless transparent single crystals of Ba.^ALN*] (Pnna, No. 52, a = 617.9(2), b = 1005.2(4), c = 1023.0(4) pm; Z = 4) were obtained from reactions of mixtures of the representative metals with nitrogen at Tmax = 1000 °C. The crystal structure of CaöfALNft] contains isolated units [ALNftJ12-built of two edge-sharing tetrahedra. Ba3[ALN4] is an isotype of S r^A bN ^. The crystal structure contains infinite chains ^ [A1N^T2] of trans edge-sharing tetrahedra. | | | |
Reference
| Z. Naturforsch. 54b, 461—465 (1999); received December 18 1998 | | | |
Published
| 1999 | | | |
Keywords
| Nitridoaluminates, Preparation, Crystal Structure | | | |
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| default:Reihe_B/54/ZNB-1999-54b-0461.pdf | | | | Identifier
| ZNB-1999-54b-0461 | | | | Volume
| 54 | |
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