| | 1 | Author
| Béla Baján, H.-Jürgen Meyer | Requires cookie* | | | Title
| Neue Niob-und Tantalchloride der  | | | | Abstract
| Zusammensetzung A4[M6C118] (A = (Ga,) In, TI; M = Nb, Ta) New Niobium and Tantalum Chlorides of the Composition A4[M6C118] (A = (Ga,) In, TI; M = Nb, Ta) The syntheses of new compounds of the general formula A4[Nb6Cli8] (A = Ga, In, Tl) and A4[TaöCli8] (A = In, Tl) are reported. The indexing of their X-ray powder patterns was performed isotypically with K^NböClis]-A single-crystal structure refinement on In4[Ta6Clis] gave the space group C2/m, Z -2, a = 1077.7(3) pm, b = 1542.3(5) pm, c = 960.2(2) pm, ß = 117.68(2) . The structure contains [TaöCliiClö] strongly distorted coordination sphere of Cl -. | | | |
Reference
| Z. Naturforsch. 50b, 1373—1376 (1995); eingegangen am 16. Januar 1995 | | | |
Published
| 1995 | | | |
Keywords
| Niobium and Tantalum Chloride Clusters, Monovalent Ga, In, TI, Synthesis, Crystal Structure | | | |
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| default:Reihe_B/50/ZNB-1995-50b-1373.pdf | | | | Identifier
| ZNB-1995-50b-1373 | | | | Volume
| 50 | |
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