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'Niobium and Tantalum Chloride Clusters' in keywords Facet   Publication Year 1995  [X]
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1Author    Béla Baján, H.-Jürgen MeyerRequires cookie*
 Title    Neue Niob-und Tantalchloride der  
 Abstract    Zusammensetzung A4[M6C118] (A = (Ga,) In, TI; M = Nb, Ta) New Niobium and Tantalum Chlorides of the Composition A4[M6C118] (A = (Ga,) In, TI; M = Nb, Ta) The syntheses of new compounds of the general formula A4[Nb6Cli8] (A = Ga, In, Tl) and A4[TaöCli8] (A = In, Tl) are reported. The indexing of their X-ray powder patterns was performed isotypically with K^NböClis]-A single-crystal structure refinement on In4[Ta6Clis] gave the space group C2/m, Z -2, a = 1077.7(3) pm, b = 1542.3(5) pm, c = 960.2(2) pm, ß = 117.68(2) . The structure contains [TaöCliiClö] strongly distorted coordination sphere of Cl -. 
  Reference    Z. Naturforsch. 50b, 1373—1376 (1995); eingegangen am 16. Januar 1995 
  Published    1995 
  Keywords    Niobium and Tantalum Chloride Clusters, Monovalent Ga, In, TI, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1373.pdf 
 Identifier    ZNB-1995-50b-1373 
 Volume    50