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'Nickelacyclopentane' in keywords
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1979 (1)
1Author    Paul Binger, MichaelJ. Doyle, Carl Krüger, Yi-Hung TsayRequires cookie*
 Title    Metallacycloalkane, III [1] Darstellung und Charakterisierung von a.a'-Dipyridyl-Nickelacyclopentan Preparation and Characterisation of a,a'-Bipyridyl-nickelacyclopentane  
 Abstract    The title compound was synthesised from bis-l,5-cyclooctadienenickel, a,a'-bipyridyl and 1,4-dibromobutane in 83% yield and its structure determined by X-ray diffraction (a = 16.600, b = 10.837, c = 14.815 Ä; ß = 153.05°; C2/c, Z = 4; symmetry: C2 with square planar coordinated nickel; Ni-C: 1.949 A). a,a'-Bipyridylnickelcyclopentane reacts with maleic anhydride or methylacrylate under reductive elimination to give cyclobutane in 75 and 57% yield; considerable amounts of butenes are formed, in addition to cyclobutane, upon reaction with borontrifluoride-dibutylether or on thermolysis. 
  Reference    Z. Naturforsch. 34b, 1289—1292 (1979); eingegangen am 16. Mai 1979 
  Published    1979 
  Keywords    Nickelacyclopentane, Preparation, Metallacycloalkane, X-ray 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1289.pdf 
 Identifier    ZNB-1979-34b-1289 
 Volume    34