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'Nickel' in keywords

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1	Author	DennisG. Brown, Ulrich Weser	Requires cookie*
	Title	XPS Spectra of Copper and Nickel Biuret Complexes — Observations of Intense Satellite Structure in the 2P Spectrum of a Copper(III) System
	Abstract	A series of copper and nickel biuret complexes has been studied by X-ray photoelectron spectroscopy (XPS). The results include one of the first reports of the XPS spectrum of a copper(III) complex. Significantly, this diamagnetic complex exhibits intense satellite structure in both the Cu 2P3/2 and Cu 2Pi/2 regions. The isoelectronic nickel(II) complex shows no comparable satellite structure.
	Reference	Z. Naturforsch. 34b, 989—994 (1979); received March 30 1979
	Published	1979
	Keywords	Copper, Nickel, Photoelectron Spectra, Satellite
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	TEI-XML for	default:Reihe_B/34/ZNB-1979-34b-0989.pdf
	Identifier	ZNB-1979-34b-0989
	Volume	34

2	Author	U. Lehmann, Hk Müller-Buschbaum	Requires cookie*
	Title	The Structure of Nd2Ni04 and its Relationship to La2Ni04 and La2CuC>4
	Abstract	Single crystals of Nd2Ni04 were prepared by plasma and C02-LASER technique and analysed by X-ray single crystal methods. Nd2Ni04 is the first compound of the orthorhombically dis-torted La2Cu04-type.
	Reference	Z. Naturforsch. 35b, 389—390 (1980); eingegangen am 19. Dezember 1979
	Published	1980
	Keywords	Neodymium, Nickel, Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/35/ZNB-1980-35b-0389_n.pdf
	Identifier	ZNB-1980-35b-0389_n
	Volume	35

3	Author	M. Bobadilla, M. Morán	Requires cookie*
	Title	Oxidative Addition of Pseudohalogen to [P(OPh)3]4Ni
	Abstract	The title compound reacts with cyanogen halides, XCN (X = Br or I) to give the com-plexes L2(X)(CN)Ni (L = P(OPh)3, X = Br or I). The oxidative addition of (SCN)2 and (SeCN)2 to the same compound results in the formation of L2Ni(XCN)2 (X = S or Se). All the complexes have been characterized by elemental analysis, and IR, iH NMR and electronic spectra.
	Reference	Z. Naturforsch. 38b, 1069—1071 (1983); received May 13 1983
	Published	1983
	Keywords	Pseudohalogens, IR Spectra, Nickel
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-1069.pdf
	Identifier	ZNB-1983-38b-1069
	Volume	38

4	Author	Christian Dietz, FrankW. Heinemann, Andreas Grohmann	Requires cookie*
	Title	Uniform Sidearm Derivatisations in a Tetrapodal Pentaamine: Ligands with NN4 O4 Donor Sets, and a Bis(Ferrocenecarbaldehyde Aminal)
	Abstract	The tetrapodal pentaamine 2,6-C5H3N[CMe(CH2NH2)2l2 (pyN_u 1) readily reacts with four equivalents of 2-hydroxyphenyl-substituted carbonyl compounds, such as (i) 2-hydroxybenz-aldehyde, (ii) 2,4-dihydroxybenzaldehyde, (iii) 3,5-di-rm-butyl-2-hydroxybenzaldehyde, and (iv) 2-hydroxyacetophenone, to give the corresponding Schiff base derivatives with N N 4O .1 donor sets (i: 2; ii: 3, iii: 4; iv: 5). With ligand 5, two transition metal complexes (M = Ni1 (6), Cu1 1 (7)) have been isolated, which are dinuclear and contain square-planar M(N202) units, linked by a pyridine-derived spacer whose nitrogen atom is uncoordinated. The reaction of 1 with ferrocenecarbaldehyde affords, under neutral conditions and irrespective of an excess of the aldehyde present, the bis(aminal) 8 as the major product, in which the two 1,3-propylenediamine subunits of 1 have condensed with two carbaldehyde moieties to give two 1,3-diazacyclohexane rings. All compounds have been characterised by IR spectroscopy and elemental analysis, as well as 'H and l3C NMR spectroscopy (except paramagnetic 7). The crystal structures of compounds 2, 6, 7, and 8 have been determined.
	Reference	Z. Naturforsch. 55b, 1037—1044 (2000); received July 28 2000
	Published	2000
	Keywords	Nonadentate Ligand, Schiff Base, Nickel
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	TEI-XML for	default:Reihe_B/55/ZNB-2000-55b-1037.pdf
	Identifier	ZNB-2000-55b-1037
	Volume	55

5	Author	S.N S	Requires cookie*
	Title	Influence of Aqueous Mixtures of Amides on the Kinetics of Electro Reduction of N i(II) and C o(II) at d. m. e
	Abstract	Electroreduction of N i(II) and C o(II) lias been carried out in aqueous mixtures of formamide, acetamide and urea. Electrode kinetics in terms of theories of irreversible waves have been studied. After calculating the rate constants by D e l a h a y 1 and K o u t e c k y 2 treatments separately their variation with electrode potential has been used to calculate the product 'ana\ The rate constants and 'ana' calculated from two different approaches show remarkable agreement. 'ana amide content of the aqueous mixture.
	Reference	(Z. Naturforsch. 30b, 859—861 [1975]; received July 17 1975)
	Published	1975
	Keywords	Amides, Kinetics, Electro Reduction, Cobalt, Nickel
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	TEI-XML for	default:Reihe_B/30/ZNB-1975-30b-0859.pdf
	Identifier	ZNB-1975-30b-0859
	Volume	30

6	Author	Albrecht Mewis, Astrid Distler	Requires cookie*
	Title	Zur Kenntnis der Verbindungen CaNi2As2, SrNi2As2 und Ca2)3NiU)7As7
	Abstract	Investigations of the systems Ca(Sr)-Ni-As resulted in the discovery of three ternary phases. CaNi2As2 and SrNi2As2 are isotypic and crys-tallize in the ThCr2Si2-structure (space group 14/mmm) with the following constants: CaNi2As2 a = 406.5(1) pm, c= 994.9(2) pm, SrNi2As2 a = 415.4(1) pm, c = 1029.0(2) pm. Ca2.3Niu.7As7 (0= 940.4(1) pm,c= 381.6(l)pm) crystallizes in a hexagonal lattice; a Zr2Fei2P7-structure is supposed.
	Reference	Z. Naturforsch. 35b, 391—393 (1980); eingegangen am 26. November 1979
	Published	1980
	Keywords	Arsenides, Nickel, Crystal Structure, Calcium, Strontium
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	TEI-XML for	default:Reihe_B/35/ZNB-1980-35b-0391_n.pdf
	Identifier	ZNB-1980-35b-0391_n
	Volume	35

7	Author	A. Döhring, P. W. Jolly, C. Krüger, M. J. Romão	Requires cookie*
	Title	The Ni(0)—C0 2 System: Structure and Reactions of [Ni(PCy 3 ) 2 (i/ 2 -C0 2 )]
	Abstract	The reactions of a variety of bis(tricyclohexylphosphine)nickel species with C0 2 have been studied. The product of the reaction is solvent dependent: in toluene the known complex [NiL 2 (/7 : -C0 2)]-toluene (L = PCy 3) is formed while in ether or pentane a binuclear complex [(NiL 2) 2 (?;-C0 2)] results through the intermediacy of the solvent free species [NiL 2 (// 2 -C0 2)] the structure of which has been determined by X-ray crystallography.
	Reference	Z. Naturforsch. 40b, 484—488 (1985); received November 30 1984
	Published	1985
	Keywords	Carbon Dioxide Complexes, Nickel, X-Ray
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	TEI-XML for	default:Reihe_B/40/ZNB-1985-40b-0484.pdf
	Identifier	ZNB-1985-40b-0484
	Volume	40

8	Author	N., Silke Busche, Karsten Bluhm	Requires cookie*
	Title	Synthese und Kristallstruktur der ersten zinkhaltigen Pyroborate
	Abstract	ii,5Z n 0,5(6 2 0 5) UI,d C o ^ Z n o ^ I ^ O s) Synthesis and Crystal Structure of the First Zinc Containing Pyroborates Nii.5Z n0.5(B2O 5) and Coj 5Z n0.5(B2O 5) The first zinc containing pyroborates Ni! sZ n ^ B ^ O s) (A) and 5Zn0 5(B 2O 5) (B) were prepared by using a B20 3 flux technique. Single crystals were investigated by X-ray diffrac tion and showed triclinic symmetry, space group C j-P l. The structures are isotypic to C o9(B 20 5) with the lattice parameters (A) « = 331.28(6), 6 = 613.87(11), c = 922.2(2), a = 104.067(11) °, ß = 90.672(13) °, y = 92.413(12) 0 and (B) 0 = 315.89(2), 6 = 612.84(6), c = 927.72(6), a = 104.103(7) °, ß = 91.020(6) °, y = 92.540(7) °, Z = 2. All metal point positions show an octahedral oxygen coordination and a partly statistical distribution o f Zn2+ and N i2+ or C o2+, respectively. Isolated nearly planar B20 5 units connect ribbons consisting o f edge sharing metal octahedra.
	Reference	Z. Naturforsch. 50b, 1445—1449 (1995); eingegangen am 25. April 1995
	Published	1995
	Keywords	Zinc, Nickel, Cobalt, Pyroborate, Crystal Structure
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	Identifier	ZNB-1995-50b-1445
	Volume	50

9	Author	S. Meyer, Hk Müller-Buschbaum	Requires cookie*
	Title	Kurze O-O-Abstände einer gemeinsamen Polyederkante bei Verknüpfung von P 0 4-Tetraedern mit V 0 6-0ktaedern im Vanadyl-Orthophosphat C aN i(V 0)(P04)2 Short 0 -0 Distances in Edge Sharing P 0 4 Tetrahedra and V 0 6 Octahedra o f the Vanadyl- Orthophosphate C a N i(V 0 )(P 0 4)2
	Abstract	Single crystals of the new compound C aN i(V 0)(P 04)2 have been prepared by solid state reactions below the melting point of the oxide mixture in evacuated quartz tubes. X-ray inve stigations ledoto orthorhom bic symmetry, space group D2£-Pnma, a -14.113(1), b -6.408(1), c = 7.364(1) A, Z = 4. The crystal structure shows J. [N i0 4] and J. [V 0 6P20 3] polyhedra chains closely related to analogous chains in the isotypic compound CdV20 (P 0 4)2. The short V -0 distance of 1.66 A indicates a vanadyl group as the main difference to CdV20 (P 0 4)2. The short 0 -0 distance of 2,395 A of the edge-sharing P 0 4 tetrahedra and V 0 6 octahedra is discussed.
	Reference	Z. Naturforsch. 52b, 981—984 (1997); eingegangen am 12. Mai 1997
	Published	1997
	Keywords	Calcium, Nickel, Vanadium Phosphate, Crystal Structure
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	TEI-XML for	default:Reihe_B/52/ZNB-1997-52b-0981.pdf
	Identifier	ZNB-1997-52b-0981
	Volume	52

10	Author	B. Wedela, K. Sugiyamaa, Hk Müller-Buschbaum	Requires cookie*
	Title	Verknüpfung von (Te06)6-und (Te06)3(N i06)3-Sechsringen durch TeNiOp-Oktaederdoppel in Pb3Ni4i5Te2? 5 0 15 Connection of (TeOö)6 and (Te06)3(N i0 6)3 Hexagons by T eN i09 Octahedra Double in Pb3Ni4 5Te2 50 15
	Abstract	Single crystals of Pb3Ni4 5Te2 5 0 15 have been prepared by heating pellets of mixtures of PbO, T e02 and nickel hydroxide carbonate to 730 °C in air. X-ray investigations led to hexagonal
	Reference	Z. Naturforsch. 53b, 527—531 (1998); eingegangen am 11. Februar 1998
	Published	1998
	Keywords	Lead, Nickel, Tellurium Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0527.pdf
	Identifier	ZNB-1998-53b-0527
	Volume	53

11	Author	Joachim Heinickea, Attila Dala, Hans-Friedrich Kleinb, Olaf Hetcheb, Ulrich Flörkec, Hans-Jürgen Hauptc	Requires cookie*
	Title	Formation of r71-P-(2-Phosphinophenol)Ni(0)(PMe3)3 and Oxidation to cjs/fraws-Bis(2-phosphinophenolato)nickel(II) Complexes
	Abstract	o-Phosphinophenols 1 (P ^ O H) react with equimolar amounts of Ni(PMe3)4 at low tempera tures to give yellow Ni(0) complexes such as [(HO~P)Ni(PMe3)3] 2a with only P coordination of the P ^ O H ligand. Oxidation of solutions of 1 and Ni(PMe3)4 by dioxygen leads to brown bis(o-phosphinophenolato-P^O)nickel chelate complexes 3a-d. Structure elucidation by NM R is consistent with a m-square planar geometry for 3a-c and a rrans-square planar solution struc ture of the terr-butylphenylphosphino derivative 3d. The geometric isomers were distinguished by different ranges of phosphorus coordination shifts and 3lP-l3C-2 and 3IP-13C-1 coupling
	Reference	Z. Naturforsch. 54b, 1235—1243 (1999); received May 19 1999
	Published	1999
	Keywords	Phosphinophenolate, Nickel, Complexes, Structure Elucidation, Solid State Structures
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	TEI-XML for	default:Reihe_B/54/ZNB-1999-54b-1235.pdf
	Identifier	ZNB-1999-54b-1235
	Volume	54

12	Author	Hans-Ulrich Meisch, Wolfgang Reinle, Bernd-Arwed Richter	Requires cookie*
	Title	Zur Frage biogener Anreicherungen von Vanadium und Nickel in Pflanzen des Karbonzeitalters The Question of Biogenous Enrichments of Vanadium and Nickel in Plants of the Carbon Age
	Abstract	O riginal carbonaceous m aterial of fossile carbon plants from the divisions of the Equisetophyta (Calam ariaceae), Lycophyta (Lepidodendraceae, S igillariacea e), Filicophyta (F ilicatae), and Sper-matophyta (Pteridospermatae, Cordaitidae) was analyzed by atomic absorption spectroscopy on its content of the trace metals vanadium and nickel. The average V-content was found to be 1 0 to 100 fold higher than that of the neighbouring coal beds or that of the embedding materials, while the Ni-concentrations were found to be almost in the same range. The highest contents of V and N i were found in the Calamariaceae and in the Pteridospermatae. The V-and Ni-contents of the fossile carbon plants are compared to those of related recent plant genera (clubmosses, horse tails, fern s), which were analyzed by 46 representative samples. A possible biogenous enrichment of V and N i in plants of the carbon age is discussed.
	Reference	Z. Naturforsch. 33c, 616 (1978); eingegangen am 7. Juni/21. Juni 1978
	Published	1978
	Keywords	Vanadium, Nickel, Carbon, Carbon Plants, Ferns, Horsetails, Clubmosses
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	TEI-XML for	default:Reihe_C/33/ZNC-1978-33c-0616.pdf
	Identifier	ZNC-1978-33c-0616
	Volume	33

13	Author	Albrecht Mewis	Requires cookie*
	Title	Neue ternäre Phosphor-und Arsenverbindungen mit Zr2Fe12P7-Struktur New Ternary Compounds of Phosphorus and Arsenic with the Zr2Fei2P7-Structure
	Abstract	The ternary compounds Mg2.5Ni11.5P7, Ca2.1Ni11.9P7 and Ca2.3Nin.7As7 were structurally characterized. They are isotypic and crystallize in the Zr2Fei2P7-type (space group P 6) with the following constants:
	Reference	Z. Naturforsch. 35b, 620—625 (1980); eingegangen am 11. Januar 1980
	Published	1980
	Keywords	Phosphides, Arsenide, 2 A Elements, Nickel, Crystal Structure
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	TEI-XML for	default:Reihe_B/35/ZNB-1980-35b-0620.pdf
	Identifier	ZNB-1980-35b-0620
	Volume	35

14	Author	Silke Buchler, Franc Meyer, Albrecht Jacobi, Peter Kircher, Laszlo Zsolnai	Requires cookie*
	Title	Novel Dinucleating Ligand Systems Containing Two Adjacent Coordination Compartments of the Potential Triamidoamine-Type -Nickel(II) and Cobalt(II) Coordination Chemistry
	Abstract	The preparation of novel dinucleating pyrazolate ligands H5L3 -H5L8 carrying chelating side arms with appending secondary amine functions is reported. Following different synthetic routes, either CH2CF3, C6H2F3 , or CftF? moieties can be introduced as substituents at the termi nal nitrogen atoms. These systems are reminiscent of two coupled coordination compartments of the potential triamidoamine-type. Crystallographic analyses of a series of bimetallic complexes of the CH2CF3-substituted ligand H5L4 with NiCh and C0 CI2 reveal manifold coordination modes in the solid state, resulting from the facile detachment of a single or several N-donor sites from the metal centers. Coordination number sets {4/6} (in H5L4Co2CU) and {5/6} (in H4L4Ni2Cl3, H4L4Co2Cl3 and H5L4Ni2CL) are thus observed. In the non-deprotonated HsL-type systems the remaining protons are found to be scavenged by a pyrazolate-N (in H5L4Ni2CU) or an amine function of a ligand side arm (in H ^ C o iC U).
	Reference	Z. Naturforsch. 54b, 1295—1306 (1999); received June 18 1999
	Published	1999
	Keywords	Dinuclear Complexes, N-Ligands, Nickel, Cobalt, Solid-State Structures
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	TEI-XML for	default:Reihe_B/54/ZNB-1999-54b-1295.pdf
	Identifier	ZNB-1999-54b-1295
	Volume	54

15	Author	Berthold Kersting	Requires cookie*
	Title	Nickel Complexes of N-Alkylated Derivatives of 2,6-Bis(aminomethyl)- 4-te/t-butyl-thiophenol
	Abstract	The syntheses of N-alkylated derivatives of the arenethiol 4-terf-butyl-2,6-(diaminomethyl)-thiophenol and their coordination properties are reported. Compounds 4-terf-butyl-2,6-di(/V-iso-propyl-aminomethyl)thiophenol (3) and 4-terf-butyl-2-(AMsopropyl-aminomethyl)-6-hydroxy-methylthiophenol (6) react with Ni(II) salts to give compounds of composition [Ni(3)2]-2HC1 (7) and [Ni(6)2] (8). The solid-and solution-state structures of both complexes consist of mononuclear complexes with four-coordinate nickel(II) ions in approximately planar trans-N2S2 coordination environments. In contrast to the parent arenethiol 4a, the sterically more encumbered ligands do not form dinuclear complexes.
	Reference	Z. Naturforsch. 53b, 1379—1385 (1998); received June 26 1998
	Published	1998
	Keywords	Mononuclear Complexes, Nickel, Amine-Thiolate Ligands, Solid-State Structures, Solution-State Structures
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-1379.pdf
	Identifier	ZNB-1998-53b-1379
	Volume	53